Th@D5h(6)-C80: a highly symmetric fullerene cage stabilized by a single metal ion

A novel endohedral metallofullerene (mono-EMF), Th@D5h(6)-C80, has been successfully synthesized and fully characterized by mass spectrometry, single crystal X-ray diffraction, UV-vis-NIR and Raman spectroscopy and cyclic voltammetry. Single crystal XRD analysis unambiguously assigned the fullerene...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2021-07, Vol.57 (54), p.6624-6627
Hauptverfasser:	Yingjing Yan, Morales-Martínez, Roser, Zhuang, Jiaxin, Yang-Rong, Yao, Li, Xiaomeng, Poblet, Josep M, Rodríguez-Fortea, Antonio, Chen, Ning
Format:	Artikel
Sprache:	eng
Schlagworte:	Cages Crystallography Electron transfer Ions Mass spectrometry Metal ions Metallofullerenes Raman spectroscopy Single crystals
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	6627
container_issue	54
container_start_page	6624
container_title	Chemical communications (Cambridge, England)
container_volume	57
creator	Yingjing Yan Morales-Martínez, Roser Zhuang, Jiaxin Yang-Rong, Yao Li, Xiaomeng Poblet, Josep M Rodríguez-Fortea, Antonio Chen, Ning
description	A novel endohedral metallofullerene (mono-EMF), Th@D5h(6)-C80, has been successfully synthesized and fully characterized by mass spectrometry, single crystal X-ray diffraction, UV-vis-NIR and Raman spectroscopy and cyclic voltammetry. Single crystal XRD analysis unambiguously assigned the fullerene cage as D5h(6)-C80, the first example in which the highly symmetric cage is stabilized by a single metal ion. The combined experimental and theoretical studies further reveal that the D5h(6)-C80 cage, known only for its stabilization by 6-electron transfer, is stabilized by the 4-electron transfer from the encapsulated Th ion for the first time.
doi_str_mv	10.1039/d1cc02339j
format	Article
fullrecord	<record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_2540726251</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2548579460</sourcerecordid><originalsourceid>FETCH-LOGICAL-p216t-96eebb3d7b402f9b6cb0e474f776c5717208d950cf04c2b4a6aaac8561c485913</originalsourceid><addsrcrecordid>eNpdzktLw0AUBeBBFKyPjb9gwE1dROf9cKXUJxREqOCuzExuminTpGaSRf31pujKuzln8XG4CF1Qck0JtzclDYEwzu36AE0oV6KQwnwe7ru0heZCHqOTnNdkPCrNBL0v6rsHWU_VVTEz5BY7XMdVnXY47zYb6LsYcDWkBB00gINbAc698zHFbyix340-x2aVAI_YJRzb5gwdVS5lOP_LU_Tx9LiYvRTzt-fX2f282DKq-sIqAO95qb0grLJeBU9AaFFprYLUVDNiSitJqIgIzAunnHPBSEWDMNJSfoqmv7vbrv0aIPfLTcwBUnINtENeMimIZorJPb38R9ft0DXjd3tlpLZCEf4DYI1csg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2548579460</pqid></control><display><type>article</type><title>Th@D5h(6)-C80: a highly symmetric fullerene cage stabilized by a single metal ion</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Yingjing Yan ; Morales-Martínez, Roser ; Zhuang, Jiaxin ; Yang-Rong, Yao ; Li, Xiaomeng ; Poblet, Josep M ; Rodríguez-Fortea, Antonio ; Chen, Ning</creator><creatorcontrib>Yingjing Yan ; Morales-Martínez, Roser ; Zhuang, Jiaxin ; Yang-Rong, Yao ; Li, Xiaomeng ; Poblet, Josep M ; Rodríguez-Fortea, Antonio ; Chen, Ning</creatorcontrib><description>A novel endohedral metallofullerene (mono-EMF), Th@D5h(6)-C80, has been successfully synthesized and fully characterized by mass spectrometry, single crystal X-ray diffraction, UV-vis-NIR and Raman spectroscopy and cyclic voltammetry. Single crystal XRD analysis unambiguously assigned the fullerene cage as D5h(6)-C80, the first example in which the highly symmetric cage is stabilized by a single metal ion. The combined experimental and theoretical studies further reveal that the D5h(6)-C80 cage, known only for its stabilization by 6-electron transfer, is stabilized by the 4-electron transfer from the encapsulated Th ion for the first time.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d1cc02339j</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Cages ; Crystallography ; Electron transfer ; Ions ; Mass spectrometry ; Metal ions ; Metallofullerenes ; Raman spectroscopy ; Single crystals</subject><ispartof>Chemical communications (Cambridge, England), 2021-07, Vol.57 (54), p.6624-6627</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Yingjing Yan</creatorcontrib><creatorcontrib>Morales-Martínez, Roser</creatorcontrib><creatorcontrib>Zhuang, Jiaxin</creatorcontrib><creatorcontrib>Yang-Rong, Yao</creatorcontrib><creatorcontrib>Li, Xiaomeng</creatorcontrib><creatorcontrib>Poblet, Josep M</creatorcontrib><creatorcontrib>Rodríguez-Fortea, Antonio</creatorcontrib><creatorcontrib>Chen, Ning</creatorcontrib><title>Th@D5h(6)-C80: a highly symmetric fullerene cage stabilized by a single metal ion</title><title>Chemical communications (Cambridge, England)</title><description>A novel endohedral metallofullerene (mono-EMF), Th@D5h(6)-C80, has been successfully synthesized and fully characterized by mass spectrometry, single crystal X-ray diffraction, UV-vis-NIR and Raman spectroscopy and cyclic voltammetry. Single crystal XRD analysis unambiguously assigned the fullerene cage as D5h(6)-C80, the first example in which the highly symmetric cage is stabilized by a single metal ion. The combined experimental and theoretical studies further reveal that the D5h(6)-C80 cage, known only for its stabilization by 6-electron transfer, is stabilized by the 4-electron transfer from the encapsulated Th ion for the first time.</description><subject>Cages</subject><subject>Crystallography</subject><subject>Electron transfer</subject><subject>Ions</subject><subject>Mass spectrometry</subject><subject>Metal ions</subject><subject>Metallofullerenes</subject><subject>Raman spectroscopy</subject><subject>Single crystals</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdzktLw0AUBeBBFKyPjb9gwE1dROf9cKXUJxREqOCuzExuminTpGaSRf31pujKuzln8XG4CF1Qck0JtzclDYEwzu36AE0oV6KQwnwe7ru0heZCHqOTnNdkPCrNBL0v6rsHWU_VVTEz5BY7XMdVnXY47zYb6LsYcDWkBB00gINbAc698zHFbyix340-x2aVAI_YJRzb5gwdVS5lOP_LU_Tx9LiYvRTzt-fX2f282DKq-sIqAO95qb0grLJeBU9AaFFprYLUVDNiSitJqIgIzAunnHPBSEWDMNJSfoqmv7vbrv0aIPfLTcwBUnINtENeMimIZorJPb38R9ft0DXjd3tlpLZCEf4DYI1csg</recordid><startdate>20210711</startdate><enddate>20210711</enddate><creator>Yingjing Yan</creator><creator>Morales-Martínez, Roser</creator><creator>Zhuang, Jiaxin</creator><creator>Yang-Rong, Yao</creator><creator>Li, Xiaomeng</creator><creator>Poblet, Josep M</creator><creator>Rodríguez-Fortea, Antonio</creator><creator>Chen, Ning</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20210711</creationdate><title>Th@D5h(6)-C80: a highly symmetric fullerene cage stabilized by a single metal ion</title><author>Yingjing Yan ; Morales-Martínez, Roser ; Zhuang, Jiaxin ; Yang-Rong, Yao ; Li, Xiaomeng ; Poblet, Josep M ; Rodríguez-Fortea, Antonio ; Chen, Ning</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p216t-96eebb3d7b402f9b6cb0e474f776c5717208d950cf04c2b4a6aaac8561c485913</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Cages</topic><topic>Crystallography</topic><topic>Electron transfer</topic><topic>Ions</topic><topic>Mass spectrometry</topic><topic>Metal ions</topic><topic>Metallofullerenes</topic><topic>Raman spectroscopy</topic><topic>Single crystals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yingjing Yan</creatorcontrib><creatorcontrib>Morales-Martínez, Roser</creatorcontrib><creatorcontrib>Zhuang, Jiaxin</creatorcontrib><creatorcontrib>Yang-Rong, Yao</creatorcontrib><creatorcontrib>Li, Xiaomeng</creatorcontrib><creatorcontrib>Poblet, Josep M</creatorcontrib><creatorcontrib>Rodríguez-Fortea, Antonio</creatorcontrib><creatorcontrib>Chen, Ning</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yingjing Yan</au><au>Morales-Martínez, Roser</au><au>Zhuang, Jiaxin</au><au>Yang-Rong, Yao</au><au>Li, Xiaomeng</au><au>Poblet, Josep M</au><au>Rodríguez-Fortea, Antonio</au><au>Chen, Ning</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Th@D5h(6)-C80: a highly symmetric fullerene cage stabilized by a single metal ion</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2021-07-11</date><risdate>2021</risdate><volume>57</volume><issue>54</issue><spage>6624</spage><epage>6627</epage><pages>6624-6627</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A novel endohedral metallofullerene (mono-EMF), Th@D5h(6)-C80, has been successfully synthesized and fully characterized by mass spectrometry, single crystal X-ray diffraction, UV-vis-NIR and Raman spectroscopy and cyclic voltammetry. Single crystal XRD analysis unambiguously assigned the fullerene cage as D5h(6)-C80, the first example in which the highly symmetric cage is stabilized by a single metal ion. The combined experimental and theoretical studies further reveal that the D5h(6)-C80 cage, known only for its stabilization by 6-electron transfer, is stabilized by the 4-electron transfer from the encapsulated Th ion for the first time.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1cc02339j</doi><tpages>4</tpages></addata></record>
fulltext	fulltext
identifier	ISSN: 1359-7345
ispartof	Chemical communications (Cambridge, England), 2021-07, Vol.57 (54), p.6624-6627
issn	1359-7345 1364-548X
language	eng
recordid	cdi_proquest_miscellaneous_2540726251
source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Cages Crystallography Electron transfer Ions Mass spectrometry Metal ions Metallofullerenes Raman spectroscopy Single crystals
title	Th@D5h(6)-C80: a highly symmetric fullerene cage stabilized by a single metal ion
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-19T11%3A28%3A04IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Th@D5h(6)-C80:%20a%20highly%20symmetric%20fullerene%20cage%20stabilized%20by%20a%20single%20metal%20ion&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Yingjing%20Yan&rft.date=2021-07-11&rft.volume=57&rft.issue=54&rft.spage=6624&rft.epage=6627&rft.pages=6624-6627&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/d1cc02339j&rft_dat=%3Cproquest%3E2548579460%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2548579460&rft_id=info:pmid/&rfr_iscdi=true