Counterintuitive solvation effect of ionic-liquid/DMSO solvents on acidic C-H dissociation and insight into respective solvation

How would acidic bond dissociation be affected by adding a small quantity of a weakly polar ionic liquid IL (the "apparent" or "measured" dielectric constant of the IL is around 10-15) into a strongly polar molecular solvent ( e.g. , of DMSO: 46.5), or vice versa ? The answer is...

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Veröffentlicht in:	Chemical science (Cambridge) 2020-03, Vol.11 (12), p.3365-337
Hauptverfasser:	Luo, Wenzhi, Mao, Chong, Ji, Pengju, Wu, Jun-Yan, Yang, Jin-Dong, Cheng, Jin-Pei
Format:	Artikel
Sprache:	eng
Schlagworte:	Acidification Binary systems Bonding strength Chemistry Dielectric strength Ionic liquids Solvation Solvents Titration
Online-Zugang:	Volltext
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