From 1,2-difunctionalisation to cyanide-transfer cascades - Pd-catalysed cyanosulfenylation of internal (oligo)alkynes

Internal alkynes substituted by aliphatic or aromatic moieties or by heteroatoms were converted into sulphur-substituted acrylonitrile derivatives. Key is the use of Pd catalysis, which allows the addition of aromatic and aliphatic thiocyanates in an intra- and intermolecular manner. Substrates with...

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Veröffentlicht in:	Chemical science (Cambridge) 2020-02, Vol.11 (7), p.1912-1917
Hauptverfasser:	Bürger, Marcel, Loch, Maximilian N, Jones, Peter G, Werz, Daniel B
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds Alkynes Chemistry Crystallography Cyano groups Substitutes Substrates Sulfur Thiocyanates
Online-Zugang:	Volltext
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