A versatile living polymerization method for aromatic amides

Polycondensation polymers typically follow step-growth kinetics assuming all functional groups are equally likely to react with one another. If the reaction rates with the chain end can be selectively accelerated, living polymers can be obtained. Here we report on two chlorophosphonium iodide reagen...

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Veröffentlicht in:	Nature chemistry 2021-07, Vol.13 (7), p.705-713
Hauptverfasser:	Pal, Subhajit, Nguyen, Dinh Phuong Trinh, Molliet, Angélique, Alizadeh, Mahshid, Crochet, Aurélien, Ortuso, Roberto D., Petri-Fink, Alke, Kilbinger, Andreas F. M.
Format:	Artikel
Sprache:	eng
Schlagworte:	639/638/455/941 639/638/455/959 Amides Amines Amino acids Analytical Chemistry Aromatic compounds Biochemistry Block copolymers Carboxylic acids Chemistry Chemistry and Materials Science Chemistry/Food Science Chlorides Condensation polymerization Copolymers Dimers Functional groups Growth kinetics Initiators Inorganic Chemistry Iodides Monomers Organic Chemistry para-Aminobenzoic acid Phosphine Phosphines Physical Chemistry Polymers Reagents Terpolymers
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