Intercalation of lithium in InSb

The lithiation of n-type single crystalline (111) oriented specimens of InSb by direct reaction with n-butyllithium in hexane solution was performed at room temperature. The lithiation process was studied by X-ray diffraction technique, electrical measurements and scanning electron microscopy. Resis...

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Veröffentlicht in:Solid state ionics 1991, Vol.47 (1), p.57-61
Hauptverfasser: Herren, G., de Reca, N.E.Walsöe
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description The lithiation of n-type single crystalline (111) oriented specimens of InSb by direct reaction with n-butyllithium in hexane solution was performed at room temperature. The lithiation process was studied by X-ray diffraction technique, electrical measurements and scanning electron microscopy. Resistivity and Hall coefficient data enabled to evaluate the change of concentration of lithium in InSb and a diffusion coefficient of lithium in InSb at room temperature D 298K=1.09×10 −8 cm 2 s −1 in agreement with diffusion coefficient of literature data. A possible intercalation mechanism is discussed and the reversibility of the process is considered.
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subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Conductivity of specific materials
Electronic transport in condensed matter
Exact sciences and technology
Physics
title Intercalation of lithium in InSb
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