A Proton‐Responsive Pyridyl(benzamide)‐Functionalized NHC Ligand on Ir Complex for Alkylation of Ketones and Secondary Alcohols

A Cp*Ir(III) complex (1) of a newly designed ligand L1 featuring a proton‐responsive pyridyl(benzamide) appended on N‐heterocyclic carbene (NHC) has been synthesized. The molecular structure of 1 reveals a dearomatized form of the ligand. The protonation of 1 with HBF4 in tetrahydrofuran gives the c...

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Veröffentlicht in:	Chemistry : a European journal 2021-07, Vol.27 (41), p.10737-10748
Hauptverfasser:	Kaur, Mandeep, U Din Reshi, Noor, Patra, Kamaless, Bhattacherya, Arindom, Kunnikuruvan, Sooraj, Bera, Jitendra K.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohol Alcohols Alkylating agents Alkylation Benzamide Borrowing-Hydrogen Catalysts Chemical synthesis Chemistry Coordination compounds Crystallography Dehydrogenation Homogeneous Catalysis Hydrogen transfer Iridium Iridium compounds Ketones Ligands Metal-Ligand Cooperation Molecular structure NMR Nuclear magnetic resonance Pregnenolone Proton-Responsive Ligand Protonation Protons Quinoline Reaction Mechanism Reaction time Steroid hormones Substrates Testosterone Tetrahydrofuran
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