Mechanism of poly(p-phenylene sulfide) growth from p-dichlorobenzene and sodium sulfide

The chemistry of poly(p-phenylene sulfide) (PPS) growth from Na sub 2 S and p-dichlorobenzene in NMP is dominated by the ionic S sub N Ar mechanism. Consistent with this mechanism are model reactions that obey discrete second-order reaction kinetics in both independent and competition experiments. R...

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Veröffentlicht in:	Macromolecules 1991-07, Vol.24 (15), p.4242-4249
Hauptverfasser:	Fahey, Darryl R, Ash, Carlton E
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polycondensation Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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