Kinetics of free-radical copolymerization: the pseudo-kinetic rate constant method
The pseudo-kinetic rate constant method in which the kinetic treatment of a multicomponent polymerization reduces to that of a homopolymerization is a useful tool to analyse the kinetics of copolymerization. This method is applicable not only for the systems described by the terminal model for copol...
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| Veröffentlicht in: | Polymer (Guilford) 1991, Vol.32 (14), p.2641-2647 |
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| container_title | Polymer (Guilford) |
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| creator | Tobita, Hidetaka Hamielec, Archie E. |
| description | The pseudo-kinetic rate constant method in which the kinetic treatment of a multicomponent polymerization reduces to that of a homopolymerization is a useful tool to analyse the kinetics of copolymerization. This method is applicable not only for the systems described by the terminal model for copolymerization but also for those described by the higher order Markov chain statistics such as the penultimate model. It has also been clarified that this method can practically be applicable even when the effect of the chain length dependent bimolecular termination reaction is significant. |
| doi_str_mv | 10.1016/0032-3861(91)90345-J |
| format | Article |
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This method is applicable not only for the systems described by the terminal model for copolymerization but also for those described by the higher order Markov chain statistics such as the penultimate model. It has also been clarified that this method can practically be applicable even when the effect of the chain length dependent bimolecular termination reaction is significant.</description><subject>Applied sciences</subject><subject>Copolymerization</subject><subject>diffusion-controlled termination</subject><subject>Exact sciences and technology</subject><subject>free-radical polymerization</subject><subject>kinetics</subject><subject>molecular weight distribution</subject><subject>multicomponent</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouK7-Aw89iOihmo82TTwIsvi1Lgii5xCSKRvtNjXJCuuvt6XLHoWBuTzvO8yD0CnBVwQTfo0xozkTnFxIcikxK8p8vocmRFQsp1SSfTTZIYfoKMZPjDEtaTFBby-uheRMzHyd1QEgD9o6o5vM-M43mxUE96uT8-1NlpaQdRHW1udfYyoLOkFPtjHpNmUrSEtvj9FBrZsIJ9s9RR8P9--zp3zx-vg8u1vkpmA45SWpZM0IqxkviS25pEyWVhvBqeamsAWmtGJYSiNJgYUUVSWKCnMhGFArLJui87G3C_57DTGplYsGmka34NdRDQ_2l2QPFiNogo8xQK264FY6bBTBahCoBjtqsKNkP4NANe9jZ9t-HXshddCtcXGXLSnjgpQ9djti0P_64yCoaBy0BqwLYJKy3v1_5w9nUYLo</recordid><startdate>1991</startdate><enddate>1991</enddate><creator>Tobita, Hidetaka</creator><creator>Hamielec, Archie E.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>1991</creationdate><title>Kinetics of free-radical copolymerization: the pseudo-kinetic rate constant method</title><author>Tobita, Hidetaka ; Hamielec, Archie E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c430t-5179f313f3651d5692395dac862a6c4d402273099c91408987784706883e2d8d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1991</creationdate><topic>Applied sciences</topic><topic>Copolymerization</topic><topic>diffusion-controlled termination</topic><topic>Exact sciences and technology</topic><topic>free-radical polymerization</topic><topic>kinetics</topic><topic>molecular weight distribution</topic><topic>multicomponent</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tobita, Hidetaka</creatorcontrib><creatorcontrib>Hamielec, Archie E.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tobita, Hidetaka</au><au>Hamielec, Archie E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetics of free-radical copolymerization: the pseudo-kinetic rate constant method</atitle><jtitle>Polymer (Guilford)</jtitle><date>1991</date><risdate>1991</risdate><volume>32</volume><issue>14</issue><spage>2641</spage><epage>2647</epage><pages>2641-2647</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>The pseudo-kinetic rate constant method in which the kinetic treatment of a multicomponent polymerization reduces to that of a homopolymerization is a useful tool to analyse the kinetics of copolymerization. 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| ispartof | Polymer (Guilford), 1991, Vol.32 (14), p.2641-2647 |
| issn | 0032-3861 1873-2291 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Copolymerization diffusion-controlled termination Exact sciences and technology free-radical polymerization kinetics molecular weight distribution multicomponent Organic polymers Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Kinetics of free-radical copolymerization: the pseudo-kinetic rate constant method |
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