Synthesis and characterization of sulfonated activated carbon as a catalyst for bio-jet fuel production from biomass and waste plastics
•SAC catalysts were prepared using corncob which is an agricultural waste.•It is the first time that SAC catalysts were used for bio-jet fuel production.•Lower sulfonation temperature promoted higher sulfonic acid density.•SAC catalysts significantly enhanced bio-oil quality.•Bio-jet aromatics and C...
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| Veröffentlicht in: | Bioresource technology 2020-02, Vol.297, p.122411-122411, Article 122411 |
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| container_title | Bioresource technology |
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| creator | Mateo, Wendy Lei, Hanwu Villota, Elmar Qian, Moriko Zhao, Yunfeng Huo, Erguang Zhang, Qingfa Lin, Xiaona Wang, Chenxi Huang, Zhiyang |
| description | •SAC catalysts were prepared using corncob which is an agricultural waste.•It is the first time that SAC catalysts were used for bio-jet fuel production.•Lower sulfonation temperature promoted higher sulfonic acid density.•SAC catalysts significantly enhanced bio-oil quality.•Bio-jet aromatics and C9-C16 alkanes were the main compounds in bio-oil.
Sulfonated activated carbon-based catalysts were prepared by microwaved-assisted carbonization of phosphoric acid activated corncob followed by sulfonation using concentrated sulfuric acid. Sulfonation at different temperatures and times resulted in varied SO3H group density of the SAC catalysts. Sulfonation temperature showed a significant effect on the introduction of SO3H on the AC precursor while time had minor role. The SAC catalysts were characterized by means of N2 sorption analysis (specific surface area, pore-volume, average pore width), FTIR spectroscopy, SEM imaging, and sulfur analysis. The impact of catalysts SO3H density on the product distribution and bio-oil composition from the catalytic co-pyrolysis of Douglas fir and LDPE was evaluated. The highest bio-jet fuels (aromatics and C9-16 alkanes) obtained was 97.51% using the SAC catalyst sulfonated at 100 °C for 5 h. Results showed that SAC has great potential as catalyst in the co-pyrolysis of biomass and plastics for the production of jet-fuel range hydrocarbons. |
| doi_str_mv | 10.1016/j.biortech.2019.122411 |
| format | Article |
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Sulfonated activated carbon-based catalysts were prepared by microwaved-assisted carbonization of phosphoric acid activated corncob followed by sulfonation using concentrated sulfuric acid. Sulfonation at different temperatures and times resulted in varied SO3H group density of the SAC catalysts. Sulfonation temperature showed a significant effect on the introduction of SO3H on the AC precursor while time had minor role. The SAC catalysts were characterized by means of N2 sorption analysis (specific surface area, pore-volume, average pore width), FTIR spectroscopy, SEM imaging, and sulfur analysis. The impact of catalysts SO3H density on the product distribution and bio-oil composition from the catalytic co-pyrolysis of Douglas fir and LDPE was evaluated. The highest bio-jet fuels (aromatics and C9-16 alkanes) obtained was 97.51% using the SAC catalyst sulfonated at 100 °C for 5 h. Results showed that SAC has great potential as catalyst in the co-pyrolysis of biomass and plastics for the production of jet-fuel range hydrocarbons.</description><identifier>ISSN: 0960-8524</identifier><identifier>EISSN: 1873-2976</identifier><identifier>DOI: 10.1016/j.biortech.2019.122411</identifier><identifier>PMID: 31767431</identifier><language>eng</language><publisher>England: Elsevier Ltd</publisher><subject>activated carbon ; aromatic compounds ; Bio-jet fuels ; Biofuels ; Biomass ; carbonization ; Catalysis ; catalysts ; Charcoal ; Co-pyrolysis ; corn cobs ; Fourier transform infrared spectroscopy ; fuel production ; Hot Temperature ; Hydrocarbons ; Low-density polyethylene ; phosphoric acid ; Plastics ; Pseudotsuga menziesii ; pyrolysis ; sorption ; Sulfonated carbon catalyst ; sulfur ; sulfuric acid ; surface area ; technology ; temperature</subject><ispartof>Bioresource technology, 2020-02, Vol.297, p.122411-122411, Article 122411</ispartof><rights>2019 Elsevier Ltd</rights><rights>Copyright © 2019 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c486t-c51220d3a582d19e24e9145dac80fc02ce3b5743371112cc631584a27652da503</citedby><cites>FETCH-LOGICAL-c486t-c51220d3a582d19e24e9145dac80fc02ce3b5743371112cc631584a27652da503</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0960852419316414$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31767431$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Mateo, Wendy</creatorcontrib><creatorcontrib>Lei, Hanwu</creatorcontrib><creatorcontrib>Villota, Elmar</creatorcontrib><creatorcontrib>Qian, Moriko</creatorcontrib><creatorcontrib>Zhao, Yunfeng</creatorcontrib><creatorcontrib>Huo, Erguang</creatorcontrib><creatorcontrib>Zhang, Qingfa</creatorcontrib><creatorcontrib>Lin, Xiaona</creatorcontrib><creatorcontrib>Wang, Chenxi</creatorcontrib><creatorcontrib>Huang, Zhiyang</creatorcontrib><title>Synthesis and characterization of sulfonated activated carbon as a catalyst for bio-jet fuel production from biomass and waste plastics</title><title>Bioresource technology</title><addtitle>Bioresour Technol</addtitle><description>•SAC catalysts were prepared using corncob which is an agricultural waste.•It is the first time that SAC catalysts were used for bio-jet fuel production.•Lower sulfonation temperature promoted higher sulfonic acid density.•SAC catalysts significantly enhanced bio-oil quality.•Bio-jet aromatics and C9-C16 alkanes were the main compounds in bio-oil.
Sulfonated activated carbon-based catalysts were prepared by microwaved-assisted carbonization of phosphoric acid activated corncob followed by sulfonation using concentrated sulfuric acid. Sulfonation at different temperatures and times resulted in varied SO3H group density of the SAC catalysts. Sulfonation temperature showed a significant effect on the introduction of SO3H on the AC precursor while time had minor role. The SAC catalysts were characterized by means of N2 sorption analysis (specific surface area, pore-volume, average pore width), FTIR spectroscopy, SEM imaging, and sulfur analysis. The impact of catalysts SO3H density on the product distribution and bio-oil composition from the catalytic co-pyrolysis of Douglas fir and LDPE was evaluated. The highest bio-jet fuels (aromatics and C9-16 alkanes) obtained was 97.51% using the SAC catalyst sulfonated at 100 °C for 5 h. Results showed that SAC has great potential as catalyst in the co-pyrolysis of biomass and plastics for the production of jet-fuel range hydrocarbons.</description><subject>activated carbon</subject><subject>aromatic compounds</subject><subject>Bio-jet fuels</subject><subject>Biofuels</subject><subject>Biomass</subject><subject>carbonization</subject><subject>Catalysis</subject><subject>catalysts</subject><subject>Charcoal</subject><subject>Co-pyrolysis</subject><subject>corn cobs</subject><subject>Fourier transform infrared spectroscopy</subject><subject>fuel production</subject><subject>Hot Temperature</subject><subject>Hydrocarbons</subject><subject>Low-density polyethylene</subject><subject>phosphoric acid</subject><subject>Plastics</subject><subject>Pseudotsuga menziesii</subject><subject>pyrolysis</subject><subject>sorption</subject><subject>Sulfonated carbon catalyst</subject><subject>sulfur</subject><subject>sulfuric acid</subject><subject>surface area</subject><subject>technology</subject><subject>temperature</subject><issn>0960-8524</issn><issn>1873-2976</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFUcuO1DAQtBCIHQZ-YZUjlwxuO3aSG2jFS1qJA3C2PO2OxqMkHmxn0fAD_DaezS7XPXVLVdXV3cXYNfAdcNDvjru9DzETHnaCQ78DIRqAZ2wDXStr0bf6OdvwXvO6U6K5Yq9SOnLOJbTiJbsqRbeNhA37-_085wMlnyo7uwoPNlrMFP0fm32YqzBUaRmHMNtMriqQv7vv0MZ9gW2RlT7b8ZxyNYRYlbXqI5V-obE6xeAWvB80xDBdwMmm1eq3TZmq01iKx_SavRjsmOjNQ92yn58-_rj5Ut9--_z15sNtjU2nc42qHMqdtKoTDnoSDfXQKGex4wNygST3qlwmWwAQiFqC6horWq2Es4rLLXu7zi2r_VooZTP5hDSOdqawJCPKt0QnVd8-TZXl10JDcdsyvVIxhpQiDeYU_WTj2QA3l7zM0TzmZS55mTWvIrx-8Fj2E7n_sseACuH9SqDylDtP0ST0NCM5HwmzccE_5fEPdIOrPw</recordid><startdate>20200201</startdate><enddate>20200201</enddate><creator>Mateo, Wendy</creator><creator>Lei, Hanwu</creator><creator>Villota, Elmar</creator><creator>Qian, Moriko</creator><creator>Zhao, Yunfeng</creator><creator>Huo, Erguang</creator><creator>Zhang, Qingfa</creator><creator>Lin, Xiaona</creator><creator>Wang, Chenxi</creator><creator>Huang, Zhiyang</creator><general>Elsevier Ltd</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20200201</creationdate><title>Synthesis and characterization of sulfonated activated carbon as a catalyst for bio-jet fuel production from biomass and waste plastics</title><author>Mateo, Wendy ; Lei, Hanwu ; Villota, Elmar ; Qian, Moriko ; Zhao, Yunfeng ; Huo, Erguang ; Zhang, Qingfa ; Lin, Xiaona ; Wang, Chenxi ; Huang, Zhiyang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c486t-c51220d3a582d19e24e9145dac80fc02ce3b5743371112cc631584a27652da503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>activated carbon</topic><topic>aromatic compounds</topic><topic>Bio-jet fuels</topic><topic>Biofuels</topic><topic>Biomass</topic><topic>carbonization</topic><topic>Catalysis</topic><topic>catalysts</topic><topic>Charcoal</topic><topic>Co-pyrolysis</topic><topic>corn cobs</topic><topic>Fourier transform infrared spectroscopy</topic><topic>fuel production</topic><topic>Hot Temperature</topic><topic>Hydrocarbons</topic><topic>Low-density polyethylene</topic><topic>phosphoric acid</topic><topic>Plastics</topic><topic>Pseudotsuga menziesii</topic><topic>pyrolysis</topic><topic>sorption</topic><topic>Sulfonated carbon catalyst</topic><topic>sulfur</topic><topic>sulfuric acid</topic><topic>surface area</topic><topic>technology</topic><topic>temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mateo, Wendy</creatorcontrib><creatorcontrib>Lei, Hanwu</creatorcontrib><creatorcontrib>Villota, Elmar</creatorcontrib><creatorcontrib>Qian, Moriko</creatorcontrib><creatorcontrib>Zhao, Yunfeng</creatorcontrib><creatorcontrib>Huo, Erguang</creatorcontrib><creatorcontrib>Zhang, Qingfa</creatorcontrib><creatorcontrib>Lin, Xiaona</creatorcontrib><creatorcontrib>Wang, Chenxi</creatorcontrib><creatorcontrib>Huang, Zhiyang</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Bioresource technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mateo, Wendy</au><au>Lei, Hanwu</au><au>Villota, Elmar</au><au>Qian, Moriko</au><au>Zhao, Yunfeng</au><au>Huo, Erguang</au><au>Zhang, Qingfa</au><au>Lin, Xiaona</au><au>Wang, Chenxi</au><au>Huang, Zhiyang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of sulfonated activated carbon as a catalyst for bio-jet fuel production from biomass and waste plastics</atitle><jtitle>Bioresource technology</jtitle><addtitle>Bioresour Technol</addtitle><date>2020-02-01</date><risdate>2020</risdate><volume>297</volume><spage>122411</spage><epage>122411</epage><pages>122411-122411</pages><artnum>122411</artnum><issn>0960-8524</issn><eissn>1873-2976</eissn><abstract>•SAC catalysts were prepared using corncob which is an agricultural waste.•It is the first time that SAC catalysts were used for bio-jet fuel production.•Lower sulfonation temperature promoted higher sulfonic acid density.•SAC catalysts significantly enhanced bio-oil quality.•Bio-jet aromatics and C9-C16 alkanes were the main compounds in bio-oil.
Sulfonated activated carbon-based catalysts were prepared by microwaved-assisted carbonization of phosphoric acid activated corncob followed by sulfonation using concentrated sulfuric acid. Sulfonation at different temperatures and times resulted in varied SO3H group density of the SAC catalysts. Sulfonation temperature showed a significant effect on the introduction of SO3H on the AC precursor while time had minor role. The SAC catalysts were characterized by means of N2 sorption analysis (specific surface area, pore-volume, average pore width), FTIR spectroscopy, SEM imaging, and sulfur analysis. The impact of catalysts SO3H density on the product distribution and bio-oil composition from the catalytic co-pyrolysis of Douglas fir and LDPE was evaluated. The highest bio-jet fuels (aromatics and C9-16 alkanes) obtained was 97.51% using the SAC catalyst sulfonated at 100 °C for 5 h. Results showed that SAC has great potential as catalyst in the co-pyrolysis of biomass and plastics for the production of jet-fuel range hydrocarbons.</abstract><cop>England</cop><pub>Elsevier Ltd</pub><pmid>31767431</pmid><doi>10.1016/j.biortech.2019.122411</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
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| source | MEDLINE; Elsevier ScienceDirect Journals |
| subjects | activated carbon aromatic compounds Bio-jet fuels Biofuels Biomass carbonization Catalysis catalysts Charcoal Co-pyrolysis corn cobs Fourier transform infrared spectroscopy fuel production Hot Temperature Hydrocarbons Low-density polyethylene phosphoric acid Plastics Pseudotsuga menziesii pyrolysis sorption Sulfonated carbon catalyst sulfur sulfuric acid surface area technology temperature |
| title | Synthesis and characterization of sulfonated activated carbon as a catalyst for bio-jet fuel production from biomass and waste plastics |
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