Hot Isostatic Press Sintering and Properties of Silicon Nitride without Additives

Fully densified silicon nitride without additives was fabricated by means of hot isostatic pressing. The sintering process of highly pure powder was investigated with special interest in the evolution of α–β phase transformation, densification, and microstructure development. It was observed that th...

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Veröffentlicht in:Journal of the American Ceramic Society 1989-09, Vol.72 (9), p.1656-1660
Hauptverfasser: Tanaka, Isao, Pezzotti, Giuseppe, Okamoto, Taira, Miyamoto, Yoshinari, Koizumi, Mitue
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container_end_page 1660
container_issue 9
container_start_page 1656
container_title Journal of the American Ceramic Society
container_volume 72
creator Tanaka, Isao
Pezzotti, Giuseppe
Okamoto, Taira
Miyamoto, Yoshinari
Koizumi, Mitue
description Fully densified silicon nitride without additives was fabricated by means of hot isostatic pressing. The sintering process of highly pure powder was investigated with special interest in the evolution of α–β phase transformation, densification, and microstructure development. It was observed that the transformation occurred without a liquid phase below 1730°C, which corresponds to the melting point of SiO2. Above 1730°C, the densification and β‐grain elongation accelerated concurrently because of the appearance of liquid SiO2. However, full densification was attained at 1950°C together with marked grain growth. Flexural strength, microhardness, fracture toughness, and Young's modulus of sintered bodies were measured as a function of temperature. In the sintered body started from highly pure powder, excellent MOR behavior was found up to 1400°C. Impurity content of a few hundred ppm was found to be sufficient to make densification easy and to degrade high‐temperature strength.
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The sintering process of highly pure powder was investigated with special interest in the evolution of α–β phase transformation, densification, and microstructure development. It was observed that the transformation occurred without a liquid phase below 1730°C, which corresponds to the melting point of SiO2. Above 1730°C, the densification and β‐grain elongation accelerated concurrently because of the appearance of liquid SiO2. However, full densification was attained at 1950°C together with marked grain growth. Flexural strength, microhardness, fracture toughness, and Young's modulus of sintered bodies were measured as a function of temperature. In the sintered body started from highly pure powder, excellent MOR behavior was found up to 1400°C. Impurity content of a few hundred ppm was found to be sufficient to make densification easy and to degrade high‐temperature strength.</abstract><cop>Oxford, UK</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/j.1151-2916.1989.tb06298.x</doi><tpages>5</tpages></addata></record>
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source Wiley Online Library Journals Frontfile Complete; Periodicals Index Online
subjects additives
Applied sciences
Building materials. Ceramics. Glasses
Ceramic industries
Chemical industry and chemicals
Exact sciences and technology
hot isostatic pressing
mechanical properties
silicon nitride
sintering
Technical ceramics
title Hot Isostatic Press Sintering and Properties of Silicon Nitride without Additives
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