Graft modification of styrene-butadiene rubber with .GAMMA.-mercaptpropyltrimethoxysilane

Graft modification of styrene-butadiene rubber with .GAMMA.-mercaptpropyltrimethoxysilane

Styrene--butadiene rubber (SBR) was modified with gamma -mercaptpropyltrimethoxysilane ( gamma -MPS) by photo graft reaction for improvement of mechanical properties of silica filled vulcanizates. It was possible to modify the SBR compounded gamma -MPS and photo-initiator, e.g. benzophenone, under i...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Nihon Gomu Kyōkai shi 1991, Vol.64 (8), p.522-527
Hauptverfasser: KODAMA, Souji, KAWASAKI, Hitoshi, MITSUISHI, Kazuta, NISHI, Katsushi
Format: Artikel
Sprache:jpn
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 527
container_issue 8
container_start_page 522
container_title Nihon Gomu Kyōkai shi
container_volume 64
creator KODAMA, Souji
KAWASAKI, Hitoshi
MITSUISHI, Kazuta
NISHI, Katsushi
description Styrene--butadiene rubber (SBR) was modified with gamma -mercaptpropyltrimethoxysilane ( gamma -MPS) by photo graft reaction for improvement of mechanical properties of silica filled vulcanizates. It was possible to modify the SBR compounded gamma -MPS and photo-initiator, e.g. benzophenone, under irradiation of the UV fluorescent lamp. The mechanical properties of modified vulcanizates were superior to non-modified ones. It was clear that this modification remarkably improved the interaction between SBR and silica from the result of the bound rubber thickness estimated by Pliskin's method. However, because of rubber gelation, compounding must be done immediately after irradiation, and some antioxidants disturbed this modification. Graphs, Spectra. 7 ref.--AA
doi_str_mv 10.2324/gomu.64.522
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_25230963</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>25230963</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1243-9448a34a5923f5db70eac3415fad4a40241229a25abbb891b2ed3411b524bcda3</originalsourceid><addsrcrecordid>eNotkEFLxDAQhYMouOie_AM9eZHWZDKt7XFZdBV28aKgpzBpUzfQbmqSov33dllP82Aej4-PsRvBM5CA91-uH7MCsxzgjC1EWWLKEeGcLTiHKuUAH5dsGYLVnEvBc8BiwT43ntqY9K6xra0pWndIXJuEOHlzMKkeIzV2TokftTY--bFxn2Sb1W63ytLe-JqGOHg3TF30tjdx736nYDs6mGt20VIXzPL_XrH3p8e39XO6fd28rFfbtBaAMq0QS5JIeQWyzRv9wA3VEkXeUoOEHFAAVAQ5aa3LSmgwzfwWeubXdUPyit2edmeM79GEqHobatMdGdwYFOQgeVXIuXh3KtbeheBNq4YZmfykBFdHg-poUBWoZoPyD_dsZa0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>25230963</pqid></control><display><type>article</type><title>Graft modification of styrene-butadiene rubber with .GAMMA.-mercaptpropyltrimethoxysilane</title><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>Alma/SFX Local Collection</source><creator>KODAMA, Souji ; KAWASAKI, Hitoshi ; MITSUISHI, Kazuta ; NISHI, Katsushi</creator><creatorcontrib>KODAMA, Souji ; KAWASAKI, Hitoshi ; MITSUISHI, Kazuta ; NISHI, Katsushi</creatorcontrib><description>Styrene--butadiene rubber (SBR) was modified with gamma -mercaptpropyltrimethoxysilane ( gamma -MPS) by photo graft reaction for improvement of mechanical properties of silica filled vulcanizates. It was possible to modify the SBR compounded gamma -MPS and photo-initiator, e.g. benzophenone, under irradiation of the UV fluorescent lamp. The mechanical properties of modified vulcanizates were superior to non-modified ones. It was clear that this modification remarkably improved the interaction between SBR and silica from the result of the bound rubber thickness estimated by Pliskin's method. However, because of rubber gelation, compounding must be done immediately after irradiation, and some antioxidants disturbed this modification. Graphs, Spectra. 7 ref.--AA</description><identifier>ISSN: 0029-022X</identifier><identifier>EISSN: 1884-0442</identifier><identifier>DOI: 10.2324/gomu.64.522</identifier><language>jpn</language><ispartof>Nihon Gomu Kyōkai shi, 1991, Vol.64 (8), p.522-527</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4010,27900,27901,27902</link.rule.ids></links><search><creatorcontrib>KODAMA, Souji</creatorcontrib><creatorcontrib>KAWASAKI, Hitoshi</creatorcontrib><creatorcontrib>MITSUISHI, Kazuta</creatorcontrib><creatorcontrib>NISHI, Katsushi</creatorcontrib><title>Graft modification of styrene-butadiene rubber with .GAMMA.-mercaptpropyltrimethoxysilane</title><title>Nihon Gomu Kyōkai shi</title><description>Styrene--butadiene rubber (SBR) was modified with gamma -mercaptpropyltrimethoxysilane ( gamma -MPS) by photo graft reaction for improvement of mechanical properties of silica filled vulcanizates. It was possible to modify the SBR compounded gamma -MPS and photo-initiator, e.g. benzophenone, under irradiation of the UV fluorescent lamp. The mechanical properties of modified vulcanizates were superior to non-modified ones. It was clear that this modification remarkably improved the interaction between SBR and silica from the result of the bound rubber thickness estimated by Pliskin's method. However, because of rubber gelation, compounding must be done immediately after irradiation, and some antioxidants disturbed this modification. Graphs, Spectra. 7 ref.--AA</description><issn>0029-022X</issn><issn>1884-0442</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNotkEFLxDAQhYMouOie_AM9eZHWZDKt7XFZdBV28aKgpzBpUzfQbmqSov33dllP82Aej4-PsRvBM5CA91-uH7MCsxzgjC1EWWLKEeGcLTiHKuUAH5dsGYLVnEvBc8BiwT43ntqY9K6xra0pWndIXJuEOHlzMKkeIzV2TokftTY--bFxn2Sb1W63ytLe-JqGOHg3TF30tjdx736nYDs6mGt20VIXzPL_XrH3p8e39XO6fd28rFfbtBaAMq0QS5JIeQWyzRv9wA3VEkXeUoOEHFAAVAQ5aa3LSmgwzfwWeubXdUPyit2edmeM79GEqHobatMdGdwYFOQgeVXIuXh3KtbeheBNq4YZmfykBFdHg-poUBWoZoPyD_dsZa0</recordid><startdate>1991</startdate><enddate>1991</enddate><creator>KODAMA, Souji</creator><creator>KAWASAKI, Hitoshi</creator><creator>MITSUISHI, Kazuta</creator><creator>NISHI, Katsushi</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>1991</creationdate><title>Graft modification of styrene-butadiene rubber with .GAMMA.-mercaptpropyltrimethoxysilane</title><author>KODAMA, Souji ; KAWASAKI, Hitoshi ; MITSUISHI, Kazuta ; NISHI, Katsushi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1243-9448a34a5923f5db70eac3415fad4a40241229a25abbb891b2ed3411b524bcda3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>jpn</language><creationdate>1991</creationdate><toplevel>online_resources</toplevel><creatorcontrib>KODAMA, Souji</creatorcontrib><creatorcontrib>KAWASAKI, Hitoshi</creatorcontrib><creatorcontrib>MITSUISHI, Kazuta</creatorcontrib><creatorcontrib>NISHI, Katsushi</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Nihon Gomu Kyōkai shi</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>KODAMA, Souji</au><au>KAWASAKI, Hitoshi</au><au>MITSUISHI, Kazuta</au><au>NISHI, Katsushi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Graft modification of styrene-butadiene rubber with .GAMMA.-mercaptpropyltrimethoxysilane</atitle><jtitle>Nihon Gomu Kyōkai shi</jtitle><date>1991</date><risdate>1991</risdate><volume>64</volume><issue>8</issue><spage>522</spage><epage>527</epage><pages>522-527</pages><issn>0029-022X</issn><eissn>1884-0442</eissn><abstract>Styrene--butadiene rubber (SBR) was modified with gamma -mercaptpropyltrimethoxysilane ( gamma -MPS) by photo graft reaction for improvement of mechanical properties of silica filled vulcanizates. It was possible to modify the SBR compounded gamma -MPS and photo-initiator, e.g. benzophenone, under irradiation of the UV fluorescent lamp. The mechanical properties of modified vulcanizates were superior to non-modified ones. It was clear that this modification remarkably improved the interaction between SBR and silica from the result of the bound rubber thickness estimated by Pliskin's method. However, because of rubber gelation, compounding must be done immediately after irradiation, and some antioxidants disturbed this modification. Graphs, Spectra. 7 ref.--AA</abstract><doi>10.2324/gomu.64.522</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0029-022X
ispartof Nihon Gomu Kyōkai shi, 1991, Vol.64 (8), p.522-527
issn 0029-022X
1884-0442
language jpn
recordid cdi_proquest_miscellaneous_25230963
source Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Alma/SFX Local Collection
title Graft modification of styrene-butadiene rubber with .GAMMA.-mercaptpropyltrimethoxysilane
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-11T04%3A34%3A05IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Graft%20modification%20of%20styrene-butadiene%20rubber%20with%20.GAMMA.-mercaptpropyltrimethoxysilane&rft.jtitle=Nihon%20Gomu%20Ky%C5%8Dkai%20shi&rft.au=KODAMA,%20Souji&rft.date=1991&rft.volume=64&rft.issue=8&rft.spage=522&rft.epage=527&rft.pages=522-527&rft.issn=0029-022X&rft.eissn=1884-0442&rft_id=info:doi/10.2324/gomu.64.522&rft_dat=%3Cproquest_cross%3E25230963%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=25230963&rft_id=info:pmid/&rfr_iscdi=true