From photosensitizers to light harvesters adapting the molecular structure in all-BODIPY assemblies

Herein we detail a protocol to design dyads and triads based solely on BODIPY dyes as halogen-free singlet oxygen photosensitizers or energy transfer molecular cassettes. The conducted photonic characterization reveals the key role of the BODIPY - BODIPY linkage to finely modulate the balance betwee...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2021-05, Vol.23 (19), p.11191-11195
Hauptverfasser: Avellanal-Zaballa, Edurne, Prieto-Castañeda, Alejandro, Díaz-Norambuena, Carolina, Bañuelos, Jorge, Agarrabeitia, Antonia R, García-Moreno, Inmaculada, de la Moya, Santiago, Ortiz, María J
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container_issue 19
container_start_page 11191
container_title Physical chemistry chemical physics : PCCP
container_volume 23
creator Avellanal-Zaballa, Edurne
Prieto-Castañeda, Alejandro
Díaz-Norambuena, Carolina
Bañuelos, Jorge
Agarrabeitia, Antonia R
García-Moreno, Inmaculada
de la Moya, Santiago
Ortiz, María J
description Herein we detail a protocol to design dyads and triads based solely on BODIPY dyes as halogen-free singlet oxygen photosensitizers or energy transfer molecular cassettes. The conducted photonic characterization reveals the key role of the BODIPY - BODIPY linkage to finely modulate the balance between the triplet state population and fluorescence decay. The designed protocol enables a fine modulation of the photonic performance of BODIPY-based molecular assemblies. The choice of the spacer and building blocks leads to triads featuring tunable singlet oxygen generation and an energy transfer laser.
doi_str_mv 10.1039/d1cp00991e
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Atomic energy levels
Cassettes
Energy transfer
Fluorescence
Harvesters
Molecular structure
NMR
Nuclear magnetic resonance
Singlet oxygen
title From photosensitizers to light harvesters adapting the molecular structure in all-BODIPY assemblies
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