α‑Ca2CdP2 and β‑Ca2CdP2: Two Polymorphic Phosphide-Based Infrared Nonlinear Crystals with Distorted NLO-Active Tetrahedral Motifs Realizing Large Second Harmonic Generation Effects and Suitable Band Gaps

Two polymorphic phosphide-based infrared (IR) nonlinear optical (NLO) crystals, α-Ca2CdP2 and β-Ca2CdP2, were obtained by combining alkaline-earth metals and d10 transition metals using metal flux and metal salt flux methods, respectively. The crystal structure of α-Ca2CdP2 is orthorhombic in the sp...

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Veröffentlicht in:	Inorganic chemistry 2021-05, Vol.60 (10), p.7553-7560
Hauptverfasser:	Sun, Yingshuang, Lin, Chensheng, Chen, Jindong, Xu, Feng, Yang, Shunda, Li, Bingxuan, Yang, Guangsai, Luo, Min, Ye, Ning
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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