Chemoselective Hydro(Chloro)pentafluorosulfanylation of Diazo Compounds with Pentafluorosulfanyl Chloride

Pentafluorosulfanyl chloride (SF5Cl) is the most prevalent reagent for the incorporation of SF5 group into organic compounds. However, the preparation of SF5Cl often relies on hazardous reagents and specialized apparatus. Herein, we described a safe and practical synthesis of a bench‐stable and easy...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-07, Vol.60 (28), p.15271-15275
Hauptverfasser:	Shou, Jia‐Yi, Xu, Xiu‐Hua, Qing, Feng‐Ling
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbonyl compounds Carbonyls Catalysts Chlorides copper diazo compounds Hexanes Organic compounds pentafluorosulfanyl chloride pentafluorosulfanylation Potassium phosphate Potassium phosphates radical reactions Reagents
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