Interstellar Enolization‐Acetaldehyde (CH3CHO) and Vinyl Alcohol (H2CCH(OH)) as a Case Study

Owing to the unique conditions in cold molecular clouds, enols—the thermodynamically less stable tautomers of aldehydes and ketones—do not undergo tautomerization to their more stable tautomers in the gas phase because they cannot overcome tautomerization barriers at the low temperatures. Laboratory...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chemphyschem 2021-06, Vol.22 (12), p.1229-1236
Hauptverfasser:	Kleimeier, N. Fabian, Kaiser, Ralf I.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetaldehyde Aldehydes Astrochemistry Chemistry Chemistry, Physical Comets complex organic molecules Cosmic rays Deep space Electrons enolization Galactic cosmic rays Ice Interstellar chemistry Interstellar matter IR spectroscopy Ketones Low temperature mass spectrometry Meteorites Molecular clouds non-equilibrium processes Physical Sciences Physics Physics, Atomic, Molecular & Chemical Radio telescopes Reaction mechanisms Science & Technology Tautomers Vapor phases
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!