Recent advances in the copper-catalyzed aerobic Csp3–H oxidation strategy

The interplay between copper catalysts and molecular oxygen provides the opportunity to control the promiscuous catalytic behaviors in aerobic Csp3–H bond oxidations without using stoichiometric amounts of oxidants. This mini-review aims to cover the Cu-catalyzed aerobic benzylic and α-carbonyl Csp3...

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Veröffentlicht in:	Organic & biomolecular chemistry 2021-04, Vol.19 (16), p.3569-3583
Hauptverfasser:	Hun Young Kim, Oh, Kyungsoo
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbonyl compounds Carbonyls Cascade chemical reactions Catalysts Copper Hydrogen bonds Oxidants Oxidation Oxidizing agents Oxygen
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description	The interplay between copper catalysts and molecular oxygen provides the opportunity to control the promiscuous catalytic behaviors in aerobic Csp3–H bond oxidations without using stoichiometric amounts of oxidants. This mini-review aims to cover the Cu-catalyzed aerobic benzylic and α-carbonyl Csp3–H oxidations and that of the carbon next to an amine group in the past five years. The development of tandem multicomponent reactions employing aerobic Csp3–H bond oxidations will be discussed to highlight the controlled catalyst behaviors and the catalyst interactions between multiple reaction components.
doi_str_mv	10.1039/d1ob00081k
format	Article
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source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Carbonyl compounds Carbonyls Cascade chemical reactions Catalysts Copper Hydrogen bonds Oxidants Oxidation Oxidizing agents Oxygen
title	Recent advances in the copper-catalyzed aerobic Csp3–H oxidation strategy
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