Efficient Copolymerization of Acrylate and Ethylene with Neutral P, O‑Chelated Nickel Catalysts: Mechanistic Investigations of Monomer Insertion and Chelate Formation

The efficient copolymerization of acrylates with ethylene using Ni catalysts remains a challenge. Herein, we report two neutral Ni­(II) catalysts (POP-Ni-py (1) and PONap-Ni-py (2)) that exhibit high thermal stability and significantly higher incorporation of polar monomer (for 1) or improved resist...

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Veröffentlicht in:	Journal of the American Chemical Society 2021-05, Vol.143 (17), p.6516-6527
Hauptverfasser:	Xiong, Shuoyan, Shoshani, Manar M, Zhang, Xinglong, Spinney, Heather A, Nett, Alex J, Henderson, Briana S, Miller, Thomas F, Agapie, Theodor
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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