H‑Bond-Mediated Selectivity Control of Formate versus CO during CO2 Photoreduction with Two Cooperative Cu/X Sites

It is highly desirable to achieve solar-driven conversion of CO2 to valuable fuels with controlled selectivity. The existing catalysts are mainly explored for CO production but rarely for formate generation. Herein, highly selective photoreduction of CO2 to formate (99.7%) was achieved with a high y...

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Veröffentlicht in:Journal of the American Chemical Society 2021-04, Vol.143 (16), p.6114-6122
Hauptverfasser: Zhuo, Tian-Ci, Song, Yang, Zhuang, Gui-Lin, Chang, Lu-Ping, Yao, Shuang, Zhang, Wei, Wang, Ye, Wang, Ping, Lin, Wenbin, Lu, Tong-Bu, Zhang, Zhi-Ming
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Sprache:eng
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