Stimuli‐Responsive Topological Transformation of a Molecular Borromean Ring via Controlled Oxidation of Thioether Moieties
A Cp*‐Rh based D‐shaped binuclear metallacycle and a template‐free molecular Borromean ring (BR) were obtained in high yield using the semi‐rigid thioether dipyridyl ligand 1,4‐bis[(pyridin‐4‐ylthio)methyl]benzene (Bptmb). The topological transformation from a binuclear metallacycle and a BR to tetr...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2021-07, Vol.60 (28), p.15466-15471 |
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| creator | Zhang, Hai‐Ning Yu, Wei‐Bin Lin, Yue‐Jian Jin, Guo‐Xin |
| description | A Cp*‐Rh based D‐shaped binuclear metallacycle and a template‐free molecular Borromean ring (BR) were obtained in high yield using the semi‐rigid thioether dipyridyl ligand 1,4‐bis[(pyridin‐4‐ylthio)methyl]benzene (Bptmb). The topological transformation from a binuclear metallacycle and a BR to tetranuclear metallacycles was realized via the controlled oxidation of thioethers. The strategy used in this work can be regarded as a new form of stimuli‐responsive post‐synthesis modification (PSM).
The controlled oxidation from thioether to sulfoxide and sulfone groups is a new post‐synthetic modification to achieve the stimuli‐responsive structural transformation from the molecular Borromean ring to tetranuclear metallacycles. |
| doi_str_mv | 10.1002/anie.202103264 |
| format | Article |
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The controlled oxidation from thioether to sulfoxide and sulfone groups is a new post‐synthetic modification to achieve the stimuli‐responsive structural transformation from the molecular Borromean ring to tetranuclear metallacycles.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202103264</identifier><identifier>PMID: 33871131</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Benzene ; Borromean ring ; controlled oxidation ; Organometallic compounds ; Oxidation ; post-synthesis modification ; Rings (mathematics) ; Stimuli ; supramolecular transformation ; thioether moieties ; Thioethers ; Topology</subject><ispartof>Angewandte Chemie International Edition, 2021-07, Vol.60 (28), p.15466-15471</ispartof><rights>2021 Wiley‐VCH GmbH</rights><rights>2021 Wiley-VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3734-fbab7ef46ba13e1c2d61662037a2c945b6a247bd71cd69803ee16ed9b232b90f3</citedby><cites>FETCH-LOGICAL-c3734-fbab7ef46ba13e1c2d61662037a2c945b6a247bd71cd69803ee16ed9b232b90f3</cites><orcidid>0000-0002-7149-5413</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202103264$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202103264$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33871131$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Hai‐Ning</creatorcontrib><creatorcontrib>Yu, Wei‐Bin</creatorcontrib><creatorcontrib>Lin, Yue‐Jian</creatorcontrib><creatorcontrib>Jin, Guo‐Xin</creatorcontrib><title>Stimuli‐Responsive Topological Transformation of a Molecular Borromean Ring via Controlled Oxidation of Thioether Moieties</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>A Cp*‐Rh based D‐shaped binuclear metallacycle and a template‐free molecular Borromean ring (BR) were obtained in high yield using the semi‐rigid thioether dipyridyl ligand 1,4‐bis[(pyridin‐4‐ylthio)methyl]benzene (Bptmb). The topological transformation from a binuclear metallacycle and a BR to tetranuclear metallacycles was realized via the controlled oxidation of thioethers. The strategy used in this work can be regarded as a new form of stimuli‐responsive post‐synthesis modification (PSM).
The controlled oxidation from thioether to sulfoxide and sulfone groups is a new post‐synthetic modification to achieve the stimuli‐responsive structural transformation from the molecular Borromean ring to tetranuclear metallacycles.</description><subject>Benzene</subject><subject>Borromean ring</subject><subject>controlled oxidation</subject><subject>Organometallic compounds</subject><subject>Oxidation</subject><subject>post-synthesis modification</subject><subject>Rings (mathematics)</subject><subject>Stimuli</subject><subject>supramolecular transformation</subject><subject>thioether moieties</subject><subject>Thioethers</subject><subject>Topology</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1DAUhS0Eou3AliWyxIZNBv_FTpZlVKBSoVIZ1pGT3LSuHN_BTgqVWPQReMY-SV1NmUrdsLp38Z2jI32EvOFsyRkTH2xwsBRMcCaFVs_IPi8FL6Qx8nn-lZSFqUq-Rw5Susx8VTH9kuxJWRnOJd8nf75Pbpy9u735ewZpgyG5K6Br3KDHc9dZT9fRhjRgHO3kMFAcqKVf0UM3exvpR4wRR7CBnrlwTq-cpSsMU0Tvoaenv12_i60vHMJ0ATHHHUwO0ivyYrA-weuHuyA_Ph2tV1-Kk9PPx6vDk6KTRqpiaG1rYFC6tVwC70SvudaCSWNFV6uy1VYo0_aGd72uKyYBuIa-boUUbc0GuSDvt72biD9nSFMzutSB9zYAzqkRJS-ZKSslMvruCXqJcwx5XaZUqYw2edOCLLdUFzGlCEOziW608brhrLn30tx7aXZecuDtQ-3cjtDv8H8iMlBvgV_Ow_V_6prDb8dHj-V3dk6cSQ</recordid><startdate>20210705</startdate><enddate>20210705</enddate><creator>Zhang, Hai‐Ning</creator><creator>Yu, Wei‐Bin</creator><creator>Lin, Yue‐Jian</creator><creator>Jin, Guo‐Xin</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-7149-5413</orcidid></search><sort><creationdate>20210705</creationdate><title>Stimuli‐Responsive Topological Transformation of a Molecular Borromean Ring via Controlled Oxidation of Thioether Moieties</title><author>Zhang, Hai‐Ning ; Yu, Wei‐Bin ; Lin, Yue‐Jian ; Jin, Guo‐Xin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3734-fbab7ef46ba13e1c2d61662037a2c945b6a247bd71cd69803ee16ed9b232b90f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Benzene</topic><topic>Borromean ring</topic><topic>controlled oxidation</topic><topic>Organometallic compounds</topic><topic>Oxidation</topic><topic>post-synthesis modification</topic><topic>Rings (mathematics)</topic><topic>Stimuli</topic><topic>supramolecular transformation</topic><topic>thioether moieties</topic><topic>Thioethers</topic><topic>Topology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Hai‐Ning</creatorcontrib><creatorcontrib>Yu, Wei‐Bin</creatorcontrib><creatorcontrib>Lin, Yue‐Jian</creatorcontrib><creatorcontrib>Jin, Guo‐Xin</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Hai‐Ning</au><au>Yu, Wei‐Bin</au><au>Lin, Yue‐Jian</au><au>Jin, Guo‐Xin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Stimuli‐Responsive Topological Transformation of a Molecular Borromean Ring via Controlled Oxidation of Thioether Moieties</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2021-07-05</date><risdate>2021</risdate><volume>60</volume><issue>28</issue><spage>15466</spage><epage>15471</epage><pages>15466-15471</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>A Cp*‐Rh based D‐shaped binuclear metallacycle and a template‐free molecular Borromean ring (BR) were obtained in high yield using the semi‐rigid thioether dipyridyl ligand 1,4‐bis[(pyridin‐4‐ylthio)methyl]benzene (Bptmb). The topological transformation from a binuclear metallacycle and a BR to tetranuclear metallacycles was realized via the controlled oxidation of thioethers. The strategy used in this work can be regarded as a new form of stimuli‐responsive post‐synthesis modification (PSM).
The controlled oxidation from thioether to sulfoxide and sulfone groups is a new post‐synthetic modification to achieve the stimuli‐responsive structural transformation from the molecular Borromean ring to tetranuclear metallacycles.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>33871131</pmid><doi>10.1002/anie.202103264</doi><tpages>6</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-7149-5413</orcidid></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Benzene Borromean ring controlled oxidation Organometallic compounds Oxidation post-synthesis modification Rings (mathematics) Stimuli supramolecular transformation thioether moieties Thioethers Topology |
| title | Stimuli‐Responsive Topological Transformation of a Molecular Borromean Ring via Controlled Oxidation of Thioether Moieties |
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