Azo‐hydrazone molecular switches: Synthesis and NMR conformational investigation

A series of five intramolecularly hydrogen‐bonded arylhydrazone (aryl = phenol, p‐nitrophenol, anisole, quinoline) derived molecular switches have been synthesized and characterized by NMR and HRMS techniques. It was found that the compounds exist as different isomers in solution. An investigation o...

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Veröffentlicht in:	Magnetic resonance in chemistry 2021-11, Vol.59 (11), p.1116-1125
Hauptverfasser:	Kurutos, Atanas, Kamounah, Fadhil S., Dobrikov, Georgi M., Pittelkow, Michael, Sauer, Stephan P. A., Hansen, Poul Erik
Format:	Artikel
Sprache:	eng
Schlagworte:	13C‐NMR 1H‐NMR 2D‐NMR Anions Anisole azo‐dyes Chemical synthesis Deuterium Hydrazones Hydrogen Hydrogen bonding Isomers isotope effect Mathematical analysis Molecular machines molecular switches Nitrophenol NMR Nuclear magnetic resonance Quantum mechanics Quinoline Solvent effect Solvents Switches
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