Interweaving Visible‐Light and Iron Catalysis for Nitrene Formation and Transformation with Dioxazolones

Herein, visible‐light‐driven iron‐catalyzed nitrene transfer reactions with dioxazolones for intermolecular C(sp3)‐N, N=S, and N=P bond formation are described. These reactions occur with exogenous‐ligand‐free process and feature satisfactory to excellent yields (up to 99 %), an ample substrate scop...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-07, Vol.60 (30), p.16426-16435
Hauptverfasser:	Tang, Jing‐Jing, Yu, Xiaoqiang, Wang, Yi, Yamamoto, Yoshinori, Bao, Ming
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemical reactions Computer applications Decarboxylation dioxazolones Iron iron catalysis Irradiation Light irradiation nitrene transfer Radiation spin state interconverting Substrates visible light
Online-Zugang:	Volltext
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