Crumpled Versus Flat Gold Nanosheets: Temperature-Regulated Synthesis and Their Plasmonic and Catalytic Properties

We report a high-yield synthesis of gold (Au) nanosheets with tunable size and surface morphology in the aqueous phase. In particular, crumpled and flat Au nanosheets with a thickness of ∼10 nm could be selectively produced in high purity when the reaction was conducted at room temperature and in an...

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Veröffentlicht in:Langmuir 2021-04, Vol.37 (14), p.4227-4235
Hauptverfasser: Zhang, Gongguo, Ma, Yanyun, Li, Mengfan, Ren, Shan, Fu, Xiaowei, Huang, Hongwen, Zheng, Yiqun
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container_end_page 4235
container_issue 14
container_start_page 4227
container_title Langmuir
container_volume 37
creator Zhang, Gongguo
Ma, Yanyun
Li, Mengfan
Ren, Shan
Fu, Xiaowei
Huang, Hongwen
Zheng, Yiqun
description We report a high-yield synthesis of gold (Au) nanosheets with tunable size and surface morphology in the aqueous phase. In particular, crumpled and flat Au nanosheets with a thickness of ∼10 nm could be selectively produced in high purity when the reaction was conducted at room temperature and in an ice–water bath, respectively. Unlike Au nanoplates/nanoprisms in the form of well-defined triangles or hexagons documented in previous studies, the current products exhibit random in-plane branches or holes, together with wavy edges. Strong absorbance in the NIR region was observed for all the Au nanosheet products. When serving as electrocatalysts for the ethanol oxidation reaction, the current products exhibited an enhanced activity and operation stability, as compared to quasi-spherical counterparts.
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title Crumpled Versus Flat Gold Nanosheets: Temperature-Regulated Synthesis and Their Plasmonic and Catalytic Properties
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