The effects of saponin, antimony and glue on zinc electrowinning from Kidd Creek electrolyte

The effects of Saponin alone and in combination with Sb and glue on Zn deposition current efficiency and polarization and on the morphology and orientation of 6 and 24 h Zn deposits electrowon at 500 A m exp --2 and 38 deg C from Kidd Creek Zn electrolyte were determined. Saponin, at concentrations...

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Veröffentlicht in:Journal of applied electrochemistry 1990-11, Vol.20 (6), p.955-963
Hauptverfasser: Mackinnon, D. J., Morrison, R. M., Mouland, J. E., Warren, P. E.
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container_issue 6
container_start_page 955
container_title Journal of applied electrochemistry
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creator Mackinnon, D. J.
Morrison, R. M.
Mouland, J. E.
Warren, P. E.
description The effects of Saponin alone and in combination with Sb and glue on Zn deposition current efficiency and polarization and on the morphology and orientation of 6 and 24 h Zn deposits electrowon at 500 A m exp --2 and 38 deg C from Kidd Creek Zn electrolyte were determined. Saponin, at concentrations to 100 mg l exp --1 , was weakly polarizing, changed the preferred deposit orientation from basal to intermediate and decreased the current efficiency. At optimum glue + Sb levels, Saponin concentrations = > 5 mg l exp --1 resulted in an increase in Zn deposition current efficiency and consistently gave either a < 114 > < 112 > < 103 > < 102 > < 101 > or a < 101 > < 112 > preferred deposit orientation depending on the Sb + glue combination used. Tests run for 24 h for selected combinations of Saponin, Sb and glue confirmed the results obtained for the 6 h studies. Graphs, Photomicrographs. 6 ref.--AA
doi_str_mv 10.1007/BF01019571
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title The effects of saponin, antimony and glue on zinc electrowinning from Kidd Creek electrolyte
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