First-passage time theory of activated rate chemical processes in electronic molecular junctions

Confined nanoscale spaces, electric fields, and tunneling currents make the molecular electronic junction an experimental device for the discovery of new out-of-equilibrium chemical reactions. Reaction-rate theory for current-activated chemical reactions is developed by combining the Keldysh nonequi...

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Veröffentlicht in:	The Journal of chemical physics 2021-03, Vol.154 (11), p.114108-114108
Hauptverfasser:	Preston, Riley J., Gelin, Maxim F., Kosov, Daniel S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Brownian motion Chemical reactions Diffusion Diffusion coefficient Electric fields Electrical junctions Fokker-Planck equation Inhomogeneous media Molecular orbitals Rate theory Temperature dependence
Online-Zugang:	Volltext
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