Study of the methanol adsorbates on Pt(100) and Pt(111) single crystal surfaces

The formation of methanol adsorbate as a structure sensitive process was studied on platinum single crystal surfaces. The measurements were performed on reproducibly prepared, clean and either well ordered (“undisturbed”) or cycled (“disturbed”) Pt(100) and Pt(111) single crystal electrodes. Essenti...

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Veröffentlicht in:	Electrochimica acta 1988-11, Vol.33 (11), p.1499-1506
Hauptverfasser:	Bittins-Cattaneo, B., Santos, E., Vielstich, W., Linke, U.
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorption Chemistry Electrochemistry Electrodeposition Exact sciences and technology General and physical chemistry Study of interfaces Transport phenomena
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creator	Bittins-Cattaneo, B. Santos, E. Vielstich, W. Linke, U.
description	The formation of methanol adsorbate as a structure sensitive process was studied on platinum single crystal surfaces. The measurements were performed on reproducibly prepared, clean and either well ordered (“undisturbed”) or cycled (“disturbed”) Pt(100) and Pt(111) single crystal electrodes. Essential differences were found. The data are interpreted in terms of parallel pathways leading to both COH and CO as adsorbed intermediates in a ratio depending on the surface structure present on the single crystal electrode.
doi_str_mv	10.1016/0013-4686(88)80219-6
format	Article
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subjects	Adsorption Chemistry Electrochemistry Electrodeposition Exact sciences and technology General and physical chemistry Study of interfaces Transport phenomena
title	Study of the methanol adsorbates on Pt(100) and Pt(111) single crystal surfaces
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