NHC‐Catalyzed Desymmetrization of N‐Aryl Maleimides Leading to the Atroposelective Synthesis of N‐Aryl Succinimides

Although the construction of axially chiral C−C bonds leading to the atroposelective synthesis of biaryls and allied compounds are well‐known, the related synthesis of compounds bearing axially chiral C−N bonds are relatively rare. Described herein is the N‐heterocyclic carbene‐catalyzed atroposelec...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-05, Vol.60 (22), p.12264-12268
Hauptverfasser:	Barik, Soumen, Shee, Sayan, Das, Soumik, Gonnade, Rajesh G., Jindal, Garima, Mukherjee, Subrata, Biju, Akkattu T.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Aromatic compounds asymmetric catalysis axial chirality Chemical bonds Chemical synthesis desymmetrization N-heterocyclic carbenes organocatalysis Oxidation Succinimides Temperature dependence
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