Solvent influence on cationic copolymerization. I: Derivation of a rule
The influence of solvent on cationic copolymerization is investigated by theoretical methods. Mathematical expressions of the quotients of reactivity ratios, r sub 2 :r sub 1 , of a copolymerization system are derived for the gas phase and solution. Considering some knowledge about solvation energie...
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| Veröffentlicht in: | European polymer journal 1988, Vol.24 (10), p.975-978 |
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| container_end_page | 978 |
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| container_issue | 10 |
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| container_title | European polymer journal |
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| creator | BÖLKE, M HALLPAP, P HEUBLEIN, G WEISS, C |
| description | The influence of solvent on cationic copolymerization is investigated by theoretical methods. Mathematical expressions of the quotients of reactivity ratios, r sub 2 :r sub 1 , of a copolymerization system are derived for the gas phase and solution. Considering some knowledge about solvation energies of charged and uncharged species in various solvents, a rule is derived describing the changes of r sub 1 and r sub 2 : the value of r sub 2 :r sub 1 decreases on moving the copolymerization system to a more polar solvent. 16 ref.--AA |
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| ispartof | European polymer journal, 1988, Vol.24 (10), p.975-978 |
| issn | 0014-3057 1873-1945 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Copolymerization Exact sciences and technology Organic polymers Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Solvent influence on cationic copolymerization. I: Derivation of a rule |
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