A Doubly Kinetically-Gated Information Ratchet Autonomously Driven by Carbodiimide Hydration

We report a rotaxane-based information ratchet in which the macrocycle distribution is pumped away from equilibrium using a carbodiimide fuel. A carboxylate group on the axle, nonequidistant between two macrocycle binding sites, efficiently catalyzes the hydration of a carbodiimide fuel to the corre...

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Veröffentlicht in:	Journal of the American Chemical Society 2021-03, Vol.143 (11), p.4414-4420
Hauptverfasser:	Borsley, Stefan, Leigh, David A, Roberts, Benjamin M. W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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