Effect of dissolved salt on the anomalies of water at negative pressure
Adding salt to water at ambient pressure affects its thermodynamic properties. At low salt concentration, anomalies such as the density maximum are shifted to lower temperature, while at large enough salt concentration, they cannot be observed any more. Here, we investigate the effect of salt on an...
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| Veröffentlicht in: | The Journal of chemical physics 2020-05, Vol.152 (19), p.194501-194501 |
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| container_issue | 19 |
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| container_title | The Journal of chemical physics |
| container_volume | 152 |
| creator | Zaragoza, Alberto Tripathi, Chandra Shekhar Pati Gonzalez, Miguel A. Abascal, José Luis F. Caupin, Frédéric Valeriani, Chantal |
| description | Adding salt to water at ambient pressure affects its thermodynamic properties. At low salt concentration, anomalies such as the density maximum are shifted to lower temperature, while at large enough salt concentration, they cannot be observed any more. Here, we investigate the effect of salt on an anomaly recently observed in pure water at negative pressure: the existence of a sound velocity minimum along isochores. We compare experiments and simulations for an aqueous solution of sodium chloride with molality around 1.2 mol kg−1, reaching pressures beyond −100 MPa. We also discuss the origin of the minima in the sound velocity and emphasize the importance of the relative position of the temperatures of sound velocity and density anomalies. |
| doi_str_mv | 10.1063/5.0002745 |
| format | Article |
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At low salt concentration, anomalies such as the density maximum are shifted to lower temperature, while at large enough salt concentration, they cannot be observed any more. Here, we investigate the effect of salt on an anomaly recently observed in pure water at negative pressure: the existence of a sound velocity minimum along isochores. We compare experiments and simulations for an aqueous solution of sodium chloride with molality around 1.2 mol kg−1, reaching pressures beyond −100 MPa. 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| source | AIP Journals Complete; Alma/SFX Local Collection |
| subjects | Acoustic velocity Anomalies Aqueous solutions Chemical Sciences Density Engineering Sciences Physics Pressure Salt Sodium chloride Thermodynamic properties |
| title | Effect of dissolved salt on the anomalies of water at negative pressure |
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