Fabrication of target specific solid-state optical sensors using chromoionophoric probe–integrated porous monolithic polymer and silica templates for cobalt ions
The article demonstrates the design of two solid-state sensors for the capturing of industrially relevant ultra-trace Co(II) ions using porous monolithic silica and polymer templates. The mesoporous silica reveals high surface area and voluminous pore dimensions that ensures homogeneous anchoring of...
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| Veröffentlicht in: | Analytical and bioanalytical chemistry 2021-05, Vol.413 (12), p.3177-3191 |
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| creator | Sompalli, Naveen Kumar Deivasigamani, Prabhakaran |
| description | The article demonstrates the design of two solid-state sensors for the capturing of industrially relevant ultra-trace Co(II) ions using porous monolithic silica and polymer templates. The mesoporous silica reveals high surface area and voluminous pore dimensions that ensures homogeneous anchoring of 4-((5-(allylthio)-1,3,4-thiadiazol-2-yl)diazenyl)benzene-1,3-diol, as the chromoionophore. We report a first of its kind solid-state macro-/meso-porous polymer monolithic optical sensor from a monomeric chromoionophore, i.e., 2-(4-butylphenyl)diazenyl)-2-hydroxybenzylidene)hydrazine-1-carbothioamide. The monolithic solid-state sensors are characterized using HR-TEM-SAED, FE-SEM-EDAX, p-XRD, XPS,
29
Si/
13
C CPMAS NMR, FT-IR, TGA, and BET/BJH analysis. The electron microscopic images reveal a highly ordered hexagonal mesoporous network of honeycomb pattern for silica monolith, and a long-range macroporous framework with mesoporous channels for polymer monolith. The sensors offer exclusive ion-selectivity and sensitivity for trace cobalt ions, through a concentration proportionate visual color transition, with a response kinetics of ≤ 5 min. The optimization of ion-sensing performance reveals an excellent detection limit of 0.29 and 0.15 ppb for Co(II), using silica- and polymer-based monolithic sensors, respectively. The proposed sensors are tested with industrial wastewater and spent Li-ion batteries, which reveals a superior cobalt ion capturing efficiency of ≥ 99.2% (RSD: ≤ 2.07%).
Graphical abstract |
| doi_str_mv | 10.1007/s00216-021-03255-1 |
| format | Article |
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29
Si/
13
C CPMAS NMR, FT-IR, TGA, and BET/BJH analysis. The electron microscopic images reveal a highly ordered hexagonal mesoporous network of honeycomb pattern for silica monolith, and a long-range macroporous framework with mesoporous channels for polymer monolith. The sensors offer exclusive ion-selectivity and sensitivity for trace cobalt ions, through a concentration proportionate visual color transition, with a response kinetics of ≤ 5 min. The optimization of ion-sensing performance reveals an excellent detection limit of 0.29 and 0.15 ppb for Co(II), using silica- and polymer-based monolithic sensors, respectively. The proposed sensors are tested with industrial wastewater and spent Li-ion batteries, which reveals a superior cobalt ion capturing efficiency of ≥ 99.2% (RSD: ≤ 2.07%).
Graphical abstract</description><identifier>ISSN: 1618-2642</identifier><identifier>EISSN: 1618-2650</identifier><identifier>DOI: 10.1007/s00216-021-03255-1</identifier><identifier>PMID: 33677651</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Benzene ; Biochemistry ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Cobalt ; Fabrication ; Food Science ; Hydrazine ; Hydrazines ; Industrial wastes ; Industrial wastewater ; Ions ; Laboratory Medicine ; Lithium-ion batteries ; Monitoring/Environmental Analysis ; NMR ; Nuclear magnetic resonance ; Optical measuring instruments ; Optimization ; Polymers ; Rechargeable batteries ; Research Paper ; Selectivity ; Sensors ; Silica ; Silicon dioxide ; Solid state ; Wastewater ; X ray photoelectron spectroscopy</subject><ispartof>Analytical and bioanalytical chemistry, 2021-05, Vol.413 (12), p.3177-3191</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c412t-3979e2606411df26c9527eab1768ffb60dec899727fb4637b3914ff012438cf93</citedby><cites>FETCH-LOGICAL-c412t-3979e2606411df26c9527eab1768ffb60dec899727fb4637b3914ff012438cf93</cites><orcidid>0000-0001-7374-0673</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00216-021-03255-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00216-021-03255-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33677651$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Sompalli, Naveen Kumar</creatorcontrib><creatorcontrib>Deivasigamani, Prabhakaran</creatorcontrib><title>Fabrication of target specific solid-state optical sensors using chromoionophoric probe–integrated porous monolithic polymer and silica templates for cobalt ions</title><title>Analytical and bioanalytical chemistry</title><addtitle>Anal Bioanal Chem</addtitle><addtitle>Anal Bioanal Chem</addtitle><description>The article demonstrates the design of two solid-state sensors for the capturing of industrially relevant ultra-trace Co(II) ions using porous monolithic silica and polymer templates. The mesoporous silica reveals high surface area and voluminous pore dimensions that ensures homogeneous anchoring of 4-((5-(allylthio)-1,3,4-thiadiazol-2-yl)diazenyl)benzene-1,3-diol, as the chromoionophore. We report a first of its kind solid-state macro-/meso-porous polymer monolithic optical sensor from a monomeric chromoionophore, i.e., 2-(4-butylphenyl)diazenyl)-2-hydroxybenzylidene)hydrazine-1-carbothioamide. The monolithic solid-state sensors are characterized using HR-TEM-SAED, FE-SEM-EDAX, p-XRD, XPS,
29
Si/
13
C CPMAS NMR, FT-IR, TGA, and BET/BJH analysis. The electron microscopic images reveal a highly ordered hexagonal mesoporous network of honeycomb pattern for silica monolith, and a long-range macroporous framework with mesoporous channels for polymer monolith. The sensors offer exclusive ion-selectivity and sensitivity for trace cobalt ions, through a concentration proportionate visual color transition, with a response kinetics of ≤ 5 min. The optimization of ion-sensing performance reveals an excellent detection limit of 0.29 and 0.15 ppb for Co(II), using silica- and polymer-based monolithic sensors, respectively. The proposed sensors are tested with industrial wastewater and spent Li-ion batteries, which reveals a superior cobalt ion capturing efficiency of ≥ 99.2% (RSD: ≤ 2.07%).
Graphical abstract</description><subject>Analytical Chemistry</subject><subject>Benzene</subject><subject>Biochemistry</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt</subject><subject>Fabrication</subject><subject>Food Science</subject><subject>Hydrazine</subject><subject>Hydrazines</subject><subject>Industrial wastes</subject><subject>Industrial wastewater</subject><subject>Ions</subject><subject>Laboratory Medicine</subject><subject>Lithium-ion batteries</subject><subject>Monitoring/Environmental Analysis</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Optical measuring instruments</subject><subject>Optimization</subject><subject>Polymers</subject><subject>Rechargeable batteries</subject><subject>Research Paper</subject><subject>Selectivity</subject><subject>Sensors</subject><subject>Silica</subject><subject>Silicon dioxide</subject><subject>Solid state</subject><subject>Wastewater</subject><subject>X ray photoelectron spectroscopy</subject><issn>1618-2642</issn><issn>1618-2650</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kbFu1TAUhiNUREvhBRiQJRaWUB8nsZMRVZQiVWIps-U49r2unDj4OEM33oFH6JvxJJxyS5EYutiW_P2fj_VX1RvgH4BzdYacC5A1LTVvRNfV8Kw6AQl9LWTHjx7PrTiuXiLecA5dD_JFddw0UinZwUl1d2HGHKwpIS0seVZM3rnCcHU2-GAZphimGospjqW1EBkZugVTRrZhWHbM7nOaE8XTuk-kYmtOo_v142dYittlCk5sTTltyGaCYij7eyjF29llZpaJYYjkZcXNayQcmU-Z2TSaWBh58VX13JuI7vXDflp9u_h0fX5ZX339_OX841VtWxClbgY1OCG5bAEmL6QdOqGcGUHJ3vtR8snZfhiUUH5sZaPGZoDWew6ibXrrh-a0en_w0g--bw6LngNaF6NZHI2vRTtQHgahCH33H3qTtrzQdFp00Pddx9uWKHGgbE6I2Xm95jCbfKuB6_sK9aFCTYv-U6EGCr19UG_j7KbHyN_OCGgOANLVsnP539tPaH8DogCrWQ</recordid><startdate>20210501</startdate><enddate>20210501</enddate><creator>Sompalli, Naveen Kumar</creator><creator>Deivasigamani, 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Chem</addtitle><date>2021-05-01</date><risdate>2021</risdate><volume>413</volume><issue>12</issue><spage>3177</spage><epage>3191</epage><pages>3177-3191</pages><issn>1618-2642</issn><eissn>1618-2650</eissn><abstract>The article demonstrates the design of two solid-state sensors for the capturing of industrially relevant ultra-trace Co(II) ions using porous monolithic silica and polymer templates. The mesoporous silica reveals high surface area and voluminous pore dimensions that ensures homogeneous anchoring of 4-((5-(allylthio)-1,3,4-thiadiazol-2-yl)diazenyl)benzene-1,3-diol, as the chromoionophore. We report a first of its kind solid-state macro-/meso-porous polymer monolithic optical sensor from a monomeric chromoionophore, i.e., 2-(4-butylphenyl)diazenyl)-2-hydroxybenzylidene)hydrazine-1-carbothioamide. The monolithic solid-state sensors are characterized using HR-TEM-SAED, FE-SEM-EDAX, p-XRD, XPS,
29
Si/
13
C CPMAS NMR, FT-IR, TGA, and BET/BJH analysis. The electron microscopic images reveal a highly ordered hexagonal mesoporous network of honeycomb pattern for silica monolith, and a long-range macroporous framework with mesoporous channels for polymer monolith. The sensors offer exclusive ion-selectivity and sensitivity for trace cobalt ions, through a concentration proportionate visual color transition, with a response kinetics of ≤ 5 min. The optimization of ion-sensing performance reveals an excellent detection limit of 0.29 and 0.15 ppb for Co(II), using silica- and polymer-based monolithic sensors, respectively. The proposed sensors are tested with industrial wastewater and spent Li-ion batteries, which reveals a superior cobalt ion capturing efficiency of ≥ 99.2% (RSD: ≤ 2.07%).
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| subjects | Analytical Chemistry Benzene Biochemistry Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Cobalt Fabrication Food Science Hydrazine Hydrazines Industrial wastes Industrial wastewater Ions Laboratory Medicine Lithium-ion batteries Monitoring/Environmental Analysis NMR Nuclear magnetic resonance Optical measuring instruments Optimization Polymers Rechargeable batteries Research Paper Selectivity Sensors Silica Silicon dioxide Solid state Wastewater X ray photoelectron spectroscopy |
| title | Fabrication of target specific solid-state optical sensors using chromoionophoric probe–integrated porous monolithic polymer and silica templates for cobalt ions |
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