Determination of the zeta potential of planar solids in nonpolar liquids
[Display omitted] ZetaSpin determines zeta potential by measuring the streaming potential generated by rotating a disk-shaped sample about its axis while submerged in the liquid. The apparatus and procedure developed for ZetaSpin in aqueous solutions was adapted for use in highly nonpolar fluids lik...
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| Veröffentlicht in: | Journal of colloid and interface science 2021-06, Vol.592, p.271-278 |
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| container_title | Journal of colloid and interface science |
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| creator | Prieve, Dennis C. Yezer, Benjamin A. Xu, Keyi Khair, Aditya S. Schneider, James W. Sides, Paul J. |
| description | [Display omitted]
ZetaSpin determines zeta potential by measuring the streaming potential generated by rotating a disk-shaped sample about its axis while submerged in the liquid. The apparatus and procedure developed for ZetaSpin in aqueous solutions was adapted for use in highly nonpolar fluids like surfactant-doped alkanes. Perhaps most unexpected is the need for up to 10 min (instead of a fraction of one second for aqueous solutions) for the electrometer to display changes in streaming potential in response to changes in rotation speed. Four tests (suggested by theory) confirm that the potential finally reported by the electrometer was indeed the streaming potential. Compared to electrophoresis, ZetaSpin does not require a value for the Debye length, avoids the complication caused by the electric-field-dependence of electrophoretic mobility and can be used with planar samples as well as colloidal particles. |
| doi_str_mv | 10.1016/j.jcis.2021.02.044 |
| format | Article |
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ZetaSpin determines zeta potential by measuring the streaming potential generated by rotating a disk-shaped sample about its axis while submerged in the liquid. The apparatus and procedure developed for ZetaSpin in aqueous solutions was adapted for use in highly nonpolar fluids like surfactant-doped alkanes. Perhaps most unexpected is the need for up to 10 min (instead of a fraction of one second for aqueous solutions) for the electrometer to display changes in streaming potential in response to changes in rotation speed. Four tests (suggested by theory) confirm that the potential finally reported by the electrometer was indeed the streaming potential. Compared to electrophoresis, ZetaSpin does not require a value for the Debye length, avoids the complication caused by the electric-field-dependence of electrophoretic mobility and can be used with planar samples as well as colloidal particles.</description><identifier>ISSN: 0021-9797</identifier><identifier>EISSN: 1095-7103</identifier><identifier>DOI: 10.1016/j.jcis.2021.02.044</identifier><identifier>PMID: 33662831</identifier><language>eng</language><publisher>United States: Elsevier Inc</publisher><subject>Electrokinetic phenomena ; Nonpolar fluids ; Streaming potential ; Zeta potential ; ZetaSpin</subject><ispartof>Journal of colloid and interface science, 2021-06, Vol.592, p.271-278</ispartof><rights>2021 The Author(s)</rights><rights>Copyright © 2021 The Author(s). Published by Elsevier Inc. All rights reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c400t-583e472ccb3a9d6c19aecb32ffc587e63b1f17dbcc4069d9cffa98f8180b4d0e3</citedby><cites>FETCH-LOGICAL-c400t-583e472ccb3a9d6c19aecb32ffc587e63b1f17dbcc4069d9cffa98f8180b4d0e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jcis.2021.02.044$$EHTML$$P50$$Gelsevier$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,3548,27922,27923,45993</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33662831$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Prieve, Dennis C.</creatorcontrib><creatorcontrib>Yezer, Benjamin A.</creatorcontrib><creatorcontrib>Xu, Keyi</creatorcontrib><creatorcontrib>Khair, Aditya S.</creatorcontrib><creatorcontrib>Schneider, James W.</creatorcontrib><creatorcontrib>Sides, Paul J.</creatorcontrib><title>Determination of the zeta potential of planar solids in nonpolar liquids</title><title>Journal of colloid and interface science</title><addtitle>J Colloid Interface Sci</addtitle><description>[Display omitted]
ZetaSpin determines zeta potential by measuring the streaming potential generated by rotating a disk-shaped sample about its axis while submerged in the liquid. The apparatus and procedure developed for ZetaSpin in aqueous solutions was adapted for use in highly nonpolar fluids like surfactant-doped alkanes. Perhaps most unexpected is the need for up to 10 min (instead of a fraction of one second for aqueous solutions) for the electrometer to display changes in streaming potential in response to changes in rotation speed. Four tests (suggested by theory) confirm that the potential finally reported by the electrometer was indeed the streaming potential. Compared to electrophoresis, ZetaSpin does not require a value for the Debye length, avoids the complication caused by the electric-field-dependence of electrophoretic mobility and can be used with planar samples as well as colloidal particles.</description><subject>Electrokinetic phenomena</subject><subject>Nonpolar fluids</subject><subject>Streaming potential</subject><subject>Zeta potential</subject><subject>ZetaSpin</subject><issn>0021-9797</issn><issn>1095-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEURYMotlb_gAuZpZsZXzKfATfiV4WCG12HTOYFU6aTaZIK-uvN0OrSVcLNeZeXQ8glhYwCrW7W2VoZnzFgNAOWQVEckTkFXqY1hfyYzCG-pLzm9Yyceb8GoLQs-SmZ5XlVsSanc7J8wIBuYwYZjB0Sq5Pwgck3BpmMNuAQjOyndOzlIF3ibW86n5ghGeww2j5GvdnuYnZOTrTsPV4czgV5f3p8u1-mq9fnl_u7VaoKgJCWTY5FzZRqc8m7SlEuMd6Z1qpsaqzylmpad62KeMU7rrSWvNENbaAtOsB8Qa73vaOz2x36IDbGK-zjfmh3XrCCNyWUvKgiyvaoctZ7h1qMzmyk-xIUxGRQrMVkUEwGBTARDcahq0P_rt1g9zfyqywCt3sA4y8_DTrhlcFBYWccqiA6a_7r_wEBWYMQ</recordid><startdate>20210615</startdate><enddate>20210615</enddate><creator>Prieve, Dennis C.</creator><creator>Yezer, Benjamin A.</creator><creator>Xu, Keyi</creator><creator>Khair, Aditya S.</creator><creator>Schneider, James W.</creator><creator>Sides, Paul J.</creator><general>Elsevier Inc</general><scope>6I.</scope><scope>AAFTH</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20210615</creationdate><title>Determination of the zeta potential of planar solids in nonpolar liquids</title><author>Prieve, Dennis C. ; Yezer, Benjamin A. ; Xu, Keyi ; Khair, Aditya S. ; Schneider, James W. ; Sides, Paul J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c400t-583e472ccb3a9d6c19aecb32ffc587e63b1f17dbcc4069d9cffa98f8180b4d0e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Electrokinetic phenomena</topic><topic>Nonpolar fluids</topic><topic>Streaming potential</topic><topic>Zeta potential</topic><topic>ZetaSpin</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Prieve, Dennis C.</creatorcontrib><creatorcontrib>Yezer, Benjamin A.</creatorcontrib><creatorcontrib>Xu, Keyi</creatorcontrib><creatorcontrib>Khair, Aditya S.</creatorcontrib><creatorcontrib>Schneider, James W.</creatorcontrib><creatorcontrib>Sides, Paul J.</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of colloid and interface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Prieve, Dennis C.</au><au>Yezer, Benjamin A.</au><au>Xu, Keyi</au><au>Khair, Aditya S.</au><au>Schneider, James W.</au><au>Sides, Paul J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of the zeta potential of planar solids in nonpolar liquids</atitle><jtitle>Journal of colloid and interface science</jtitle><addtitle>J Colloid Interface Sci</addtitle><date>2021-06-15</date><risdate>2021</risdate><volume>592</volume><spage>271</spage><epage>278</epage><pages>271-278</pages><issn>0021-9797</issn><eissn>1095-7103</eissn><abstract>[Display omitted]
ZetaSpin determines zeta potential by measuring the streaming potential generated by rotating a disk-shaped sample about its axis while submerged in the liquid. The apparatus and procedure developed for ZetaSpin in aqueous solutions was adapted for use in highly nonpolar fluids like surfactant-doped alkanes. Perhaps most unexpected is the need for up to 10 min (instead of a fraction of one second for aqueous solutions) for the electrometer to display changes in streaming potential in response to changes in rotation speed. Four tests (suggested by theory) confirm that the potential finally reported by the electrometer was indeed the streaming potential. Compared to electrophoresis, ZetaSpin does not require a value for the Debye length, avoids the complication caused by the electric-field-dependence of electrophoretic mobility and can be used with planar samples as well as colloidal particles.</abstract><cop>United States</cop><pub>Elsevier Inc</pub><pmid>33662831</pmid><doi>10.1016/j.jcis.2021.02.044</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Electrokinetic phenomena Nonpolar fluids Streaming potential Zeta potential ZetaSpin |
| title | Determination of the zeta potential of planar solids in nonpolar liquids |
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