Polymerization of vinyl monomers initiated by peroxide-geminal bis-sulphide systems
It is found that the interaction of geminal bis-sulphides with acyl(aroyl)peroxides forms systems which initiate polymerization in non-aqueous media. The mechanism of the reaction of benzoyl peroxide with bis(amylthio)methane was studied. The initiation is shown to result form the products of the in...
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| Veröffentlicht in: | European polymer journal 1988, Vol.24 (6), p.579-583 |
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| container_end_page | 583 |
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| container_issue | 6 |
| container_start_page | 579 |
| container_title | European polymer journal |
| container_volume | 24 |
| creator | Puzin, Yu.I. Leplyanin, G.V. Shaul'skii, Yu.M. Tolstikov, G.A. |
| description | It is found that the interaction of geminal bis-sulphides with acyl(aroyl)peroxides forms systems which initiate polymerization in non-aqueous media. The mechanism of the reaction of benzoyl peroxide with bis(amylthio)methane was studied. The initiation is shown to result form the products of the interaction of the components. |
| doi_str_mv | 10.1016/0014-3057(88)90053-5 |
| format | Article |
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The mechanism of the reaction of benzoyl peroxide with bis(amylthio)methane was studied. 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The mechanism of the reaction of benzoyl peroxide with bis(amylthio)methane was studied. 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| ispartof | European polymer journal, 1988, Vol.24 (6), p.579-583 |
| issn | 0014-3057 1873-1945 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_24968507 |
| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Polymerization of vinyl monomers initiated by peroxide-geminal bis-sulphide systems |
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