Reversible Addition of Carbon Dioxide to Main Group Metal Complexes at Temperatures about 0 °C

The reaction of dialane [LAl‐AlL] (1; L=dianion of 1,2‐bis[(2,6‐diisopropylphenyl)imino]acenaphthene, dpp‐bian) with carbon dioxide results in two different products depending on solvent. In toluene at temperatures of about 0 °C, the reaction gives cycloadduct [L(CO2)Al‐Al(O2C)L] (2), whereas in die...

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Veröffentlicht in:	Chemistry : a European journal 2021-03, Vol.27 (18), p.5745-5753
Hauptverfasser:	Koptseva, Tatyana S., Sokolov, Vladimir G., Ketkov, Sergey Yu, Rychagova, Elena A., Cherkasov, Anton V., Skatova, Alexandra A., Fedushkin, Igor L.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acenaphthene Aluminum Anions Carbon dioxide Chemistry cleavage of multiple bonds Coordination compounds Cycloaddition dialanes Diethyl ether Intermediates main group elements Mathematical analysis Metal complexes Toluene
Online-Zugang:	Volltext
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