Phenomenological Calculation of L1 sub 0 -Disorder Transition Temperature in a Gold--Palladium System

A phenomenological calculation based on the tetrahedron approximation of the cluster variation method with a Lennard--Jones type energy expression was performed to calculate the transition temperature of L1 sub 0 -disorder phases in an Au--Pd system. The transition temperatures are placed between 30...

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Veröffentlicht in:Mem. Fac. Eng., Hokkaido Univ Hokkaido Univ, 1988-12, Vol.17 (3), p.297-305
Hauptverfasser: Mohri, T, Kobayashi, C, Watanabe, K
Format: Artikel
Sprache:eng
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Zusammenfassung:A phenomenological calculation based on the tetrahedron approximation of the cluster variation method with a Lennard--Jones type energy expression was performed to calculate the transition temperature of L1 sub 0 -disorder phases in an Au--Pd system. The transition temperatures are placed between 300-350K depending upon the two kinds of Lennard--Jones parameters employed. The origin of the discrepancy between the present calculation and experimental phase diagrams is discused. 15 ref.--AA
ISSN:0368-9379