Synthesis of Enynic and Allenic Orthoesters via Defluoromethoxylation of 2‑Trifluoromethyl-1,3-enynes

In this protocol, the chemoselective defluoromethoxylation reactions of 2-trifluoromethyl-1,3-enynes were developed. The enynic and allenic orthoesters were selectively produced in good to excellent yields via multiple substitution processes under mild reaction conditions, respectively. The enynic o...

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Veröffentlicht in:	Organic letters 2021-03, Vol.23 (5), p.1898-1903
Hauptverfasser:	Dai, Dong-Ting, Xu, Jian-Lin, Chen, Zhi-Yuan, Wang, Zi-Lu, Xu, Yun-He
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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