Two-Coordinate, Nonlinear Vanadium(II) and Chromium(II) Complexes of the Silylamide Ligand–N(SiMePh2)2: Characterization and Confirmation of Orbitally Quenched Magnetic Moments in Complexes with Sub‑d5 Electron Configurations

The two-coordinate metal amide complexes V­{N­(SiMePh2)2}2 (1) and Cr­{N­(SiMe2Ph)2}2 (2) were synthesized by reaction of two equivalents of LiN­(SiMePh2)2 with VI2(THF)4 or CrCl2(THF)2 in n-hexane. Their crystal structures showed that they have bent coordination, N–V–N = 137.0(4)°, N–Cr–N = 139.19(...

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Veröffentlicht in:	Inorganic chemistry 2021-03, Vol.60 (6), p.4108-4115
Hauptverfasser:	Freitag, Kerstin, Stennett, Cary R, Mansikkamäki, Akseli, Fischer, Roland A, Power, Philip P
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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