Site-Selective Acylation of Pyranosides with Oligopeptide Catalysts

Herein, we report the oligopeptide-catalyzed site-selective acylation of partially protected monosaccharides. We identified catalysts that invert site-selectivity compared to N-methylimidazole, which was used to determine the intrinsic reactivity, for 4,6-O-protected glucopyranosides (trans-diols) a...

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Veröffentlicht in:	Journal of organic chemistry 2021-03, Vol.86 (5), p.3907-3922
Hauptverfasser:	Seitz, Alexander, Wende, Raffael C, Roesner, Emily, Niedek, Dominik, Topp, Christopher, Colgan, Avene C, McGarrigle, Eoghan M, Schreiner, Peter R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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