Electrodeposition of Copper‐Nickel Alloys from Citrate Solutions on a Rotating Disk Electrode: II . Mathematical Modeling

Electrodeposition of Copper‐Nickel Alloys from Citrate Solutions on a Rotating Disk Electrode: II . Mathematical Modeling

A mathematical model is developed to simulate the electrodeposition of Cu--Ni alloy from citrate solutions onto a rotating disk electrode under potentiostatic control. The model includes the influence of diffusion, ionic migration, forced convection, and homogeneous equilibria. The three major elect...

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Veröffentlicht in:Journal of the Electrochemical Society 1988-12, Vol.135 (12), p.2964-2971
Hauptverfasser: Ying, Ramona Y., Ng, Patrick K., Mao, Z., White, Ralph E.
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container_end_page 2971
container_issue 12
container_start_page 2964
container_title Journal of the Electrochemical Society
container_volume 135
creator Ying, Ramona Y.
Ng, Patrick K.
Mao, Z.
White, Ralph E.
description A mathematical model is developed to simulate the electrodeposition of Cu--Ni alloy from citrate solutions onto a rotating disk electrode under potentiostatic control. The model includes the influence of diffusion, ionic migration, forced convection, and homogeneous equilibria. The three major electrochemical reactions treated in the model are Cu deposition, Ni deposition, and hydrogen evolution. Using experimental parameters when available, the model was fitted and tested against experimentally-obtained results for different bath compositions and operating conditions. The model agreed reasonably well with the experimental results particularly in the codeposition region, 2--1.0 to --1.2 V vs. SCE, where H evolution is not the major reaction. Also, the model's predictive capabilities are evaluated. . 14 ref.--AA
doi_str_mv 10.1149/1.2095470
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title Electrodeposition of Copper‐Nickel Alloys from Citrate Solutions on a Rotating Disk Electrode: II . Mathematical Modeling
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