High-Amylose Corn Starch/Konjac Glucomannan Composite Film: Reinforced by Incorporating β‑Cyclodextrin
Glycerol-plasticized high-amylose corn starch/konjac glucomannan (HCS/KGM) composite films incorporated with various concentrations of β-cyclodextrin (β-CD) were prepared and investigated for structural, mechanical, and physical properties. The results of X-ray diffraction, attenuated total reflecta...
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Veröffentlicht in: | Journal of agricultural and food chemistry 2021-03, Vol.69 (8), p.2493-2500 |
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creator | Zou, Yiyuan Yuan, Chao Cui, Bo Sha, Haojie Liu, Pengfei Lu, Lu Wu, Zhengzong |
description | Glycerol-plasticized high-amylose corn starch/konjac glucomannan (HCS/KGM) composite films incorporated with various concentrations of β-cyclodextrin (β-CD) were prepared and investigated for structural, mechanical, and physical properties. The results of X-ray diffraction, attenuated total reflectance Fourier transform infrared spectroscopy, thermogravimetric analyses, and scanning electron microscopy indicated that β-CD excluded from the polymer chains and aggregated to form crystals during film formation, which drove HCS to interact with KGM more compactly. The thickness and transparency of the films increased after β-CD was incorporated. More associations of HCS/KGM enhanced the mechanical properties and reduced the moisture content of the films. The water vapor permeability of the HCS/KGM composite film was also improved significantly with the incorporation of β-CD. The enhanced association between biopolymers in the presence of β-CD will advance the development of a degradable active composite packaging film. |
doi_str_mv | 10.1021/acs.jafc.0c06648 |
format | Article |
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Agric. Food Chem</addtitle><description>Glycerol-plasticized high-amylose corn starch/konjac glucomannan (HCS/KGM) composite films incorporated with various concentrations of β-cyclodextrin (β-CD) were prepared and investigated for structural, mechanical, and physical properties. The results of X-ray diffraction, attenuated total reflectance Fourier transform infrared spectroscopy, thermogravimetric analyses, and scanning electron microscopy indicated that β-CD excluded from the polymer chains and aggregated to form crystals during film formation, which drove HCS to interact with KGM more compactly. The thickness and transparency of the films increased after β-CD was incorporated. More associations of HCS/KGM enhanced the mechanical properties and reduced the moisture content of the films. The water vapor permeability of the HCS/KGM composite film was also improved significantly with the incorporation of β-CD. The enhanced association between biopolymers in the presence of β-CD will advance the development of a degradable active composite packaging film.</description><subject>Amylose</subject><subject>beta-Cyclodextrins</subject><subject>Biofuels and Biobased Materials</subject><subject>Mannans</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Starch</subject><subject>Zea mays</subject><issn>0021-8561</issn><issn>1520-5118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp1kM1O3DAURq0KVKaUPSuUZRdkuI5jj8MORfyJkZCgrCPnjj14lNiDnUjMrq_QV-mD9CH6JDWdoTs214t7vk_Xh5BjClMKBT1TGKcrZXAKCEKU8hOZUF5AzimVe2QCicklF_SAfIlxBQCSz-AzOWCMV6WUfELsjV0-5xf9pvNRZ7UPLnscVMDnszvvVgqz625E3yvnlEvrfu2jHXR2Zbv-PHvQ1hkfUC-ydpPdOvRh7YMarFtmv3_9-fGz3mDnF_p1CNZ9JftGdVEf7d5D8nR1-b2-yef317f1xTxXjIkhzTJdD1xS00ookFKjClYwijjDSgiDRUUBtDQzzVqByrSCVmnDS1qqwrBD8m3buw7-ZdRxaHobUXedctqPsSnKCgRwNmMJhS2KwccYtGnWwfYqbBoKzZvgJglu3gQ3O8EpcrJrH9teL_4H3o0m4HQL_Iv6Mbj02Y_7_gKuL4kS</recordid><startdate>20210303</startdate><enddate>20210303</enddate><creator>Zou, Yiyuan</creator><creator>Yuan, Chao</creator><creator>Cui, Bo</creator><creator>Sha, Haojie</creator><creator>Liu, Pengfei</creator><creator>Lu, Lu</creator><creator>Wu, Zhengzong</creator><general>American Chemical Society</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-1302-9668</orcidid></search><sort><creationdate>20210303</creationdate><title>High-Amylose Corn Starch/Konjac Glucomannan Composite Film: Reinforced by Incorporating β‑Cyclodextrin</title><author>Zou, Yiyuan ; Yuan, Chao ; Cui, Bo ; Sha, Haojie ; Liu, Pengfei ; Lu, Lu ; Wu, Zhengzong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a336t-a345110581fb802c11fa23231cc7c966fc29100e8f7e3b6cafb619c965414a2f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Amylose</topic><topic>beta-Cyclodextrins</topic><topic>Biofuels and Biobased Materials</topic><topic>Mannans</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Starch</topic><topic>Zea mays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zou, Yiyuan</creatorcontrib><creatorcontrib>Yuan, Chao</creatorcontrib><creatorcontrib>Cui, Bo</creatorcontrib><creatorcontrib>Sha, Haojie</creatorcontrib><creatorcontrib>Liu, Pengfei</creatorcontrib><creatorcontrib>Lu, Lu</creatorcontrib><creatorcontrib>Wu, Zhengzong</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of agricultural and food chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zou, Yiyuan</au><au>Yuan, Chao</au><au>Cui, Bo</au><au>Sha, Haojie</au><au>Liu, Pengfei</au><au>Lu, Lu</au><au>Wu, Zhengzong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High-Amylose Corn Starch/Konjac Glucomannan Composite Film: Reinforced by Incorporating β‑Cyclodextrin</atitle><jtitle>Journal of agricultural and food chemistry</jtitle><addtitle>J. Agric. Food Chem</addtitle><date>2021-03-03</date><risdate>2021</risdate><volume>69</volume><issue>8</issue><spage>2493</spage><epage>2500</epage><pages>2493-2500</pages><issn>0021-8561</issn><eissn>1520-5118</eissn><abstract>Glycerol-plasticized high-amylose corn starch/konjac glucomannan (HCS/KGM) composite films incorporated with various concentrations of β-cyclodextrin (β-CD) were prepared and investigated for structural, mechanical, and physical properties. The results of X-ray diffraction, attenuated total reflectance Fourier transform infrared spectroscopy, thermogravimetric analyses, and scanning electron microscopy indicated that β-CD excluded from the polymer chains and aggregated to form crystals during film formation, which drove HCS to interact with KGM more compactly. The thickness and transparency of the films increased after β-CD was incorporated. More associations of HCS/KGM enhanced the mechanical properties and reduced the moisture content of the films. The water vapor permeability of the HCS/KGM composite film was also improved significantly with the incorporation of β-CD. The enhanced association between biopolymers in the presence of β-CD will advance the development of a degradable active composite packaging film.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>33594885</pmid><doi>10.1021/acs.jafc.0c06648</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-1302-9668</orcidid></addata></record> |
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subjects | Amylose beta-Cyclodextrins Biofuels and Biobased Materials Mannans Spectroscopy, Fourier Transform Infrared Starch Zea mays |
title | High-Amylose Corn Starch/Konjac Glucomannan Composite Film: Reinforced by Incorporating β‑Cyclodextrin |
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