Growth of superconducting thin films of bismuth-strontium-calcium-copper oxide by organometallic chemical vapor deposition

The first growth of superconducting Bi-Sr-Ca-Cu-O films by organometallic chemical vapor deposition is described. Triphenyl bismuth and beta-diketonates of strontium, calcium, and copper were decomposed thermally at 500°C on MgO substrates in an oxygen-rich atmosphere to produce fine grained or amor...

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Veröffentlicht in:Journal of crystal growth 1988-10, Vol.92 (1), p.344-347
Hauptverfasser: Berry, A.D., Holm, R.T., Cukauskas, E.J., Fatemi, M., Gaskill, D.K., Kaplan, R., Fox, W.B.
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container_end_page 347
container_issue 1
container_start_page 344
container_title Journal of crystal growth
container_volume 92
creator Berry, A.D.
Holm, R.T.
Cukauskas, E.J.
Fatemi, M.
Gaskill, D.K.
Kaplan, R.
Fox, W.B.
description The first growth of superconducting Bi-Sr-Ca-Cu-O films by organometallic chemical vapor deposition is described. Triphenyl bismuth and beta-diketonates of strontium, calcium, and copper were decomposed thermally at 500°C on MgO substrates in an oxygen-rich atmosphere to produce fine grained or amorphous, dark brown to black films. Subsequent annealing in oxygen yielded gray-black films with thicknesses of 0.95 to 1.25 μm. X-ray analysis indicated the presence of a tetragonal superconducting phase along with other metal oxides. The sheet resistance versus temperature for the sample with the highest T c had a resistive transition with a midpoint at 78.8 K, a width of 7.7 K, and R = 0 at 73.2 K.
doi_str_mv 10.1016/0022-0248(88)90470-8
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subjects Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Thin film structure and morphology
title Growth of superconducting thin films of bismuth-strontium-calcium-copper oxide by organometallic chemical vapor deposition
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