Growth of superconducting thin films of bismuth-strontium-calcium-copper oxide by organometallic chemical vapor deposition
The first growth of superconducting Bi-Sr-Ca-Cu-O films by organometallic chemical vapor deposition is described. Triphenyl bismuth and beta-diketonates of strontium, calcium, and copper were decomposed thermally at 500°C on MgO substrates in an oxygen-rich atmosphere to produce fine grained or amor...
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Veröffentlicht in: | Journal of crystal growth 1988-10, Vol.92 (1), p.344-347 |
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container_title | Journal of crystal growth |
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creator | Berry, A.D. Holm, R.T. Cukauskas, E.J. Fatemi, M. Gaskill, D.K. Kaplan, R. Fox, W.B. |
description | The first growth of superconducting Bi-Sr-Ca-Cu-O films by organometallic chemical vapor deposition is described. Triphenyl bismuth and beta-diketonates of strontium, calcium, and copper were decomposed thermally at 500°C on MgO substrates in an oxygen-rich atmosphere to produce fine grained or amorphous, dark brown to black films. Subsequent annealing in oxygen yielded gray-black films with thicknesses of 0.95 to 1.25 μm. X-ray analysis indicated the presence of a tetragonal superconducting phase along with other metal oxides. The sheet resistance versus temperature for the sample with the highest
T
c had a resistive transition with a midpoint at 78.8 K, a width of 7.7 K, and
R = 0 at 73.2 K. |
doi_str_mv | 10.1016/0022-0248(88)90470-8 |
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T
c had a resistive transition with a midpoint at 78.8 K, a width of 7.7 K, and
R = 0 at 73.2 K.</description><identifier>ISSN: 0022-0248</identifier><identifier>EISSN: 1873-5002</identifier><identifier>DOI: 10.1016/0022-0248(88)90470-8</identifier><identifier>CODEN: JCRGAE</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Physics ; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties) ; Thin film structure and morphology</subject><ispartof>Journal of crystal growth, 1988-10, Vol.92 (1), p.344-347</ispartof><rights>1988</rights><rights>1989 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c430t-de315293e59ea4de29e2d540f6fd0685f66476b545834aa1bdc06ae05b071dcf3</citedby><cites>FETCH-LOGICAL-c430t-de315293e59ea4de29e2d540f6fd0685f66476b545834aa1bdc06ae05b071dcf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/0022-0248(88)90470-8$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27929,27930,46000</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7349344$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Berry, A.D.</creatorcontrib><creatorcontrib>Holm, R.T.</creatorcontrib><creatorcontrib>Cukauskas, E.J.</creatorcontrib><creatorcontrib>Fatemi, M.</creatorcontrib><creatorcontrib>Gaskill, D.K.</creatorcontrib><creatorcontrib>Kaplan, R.</creatorcontrib><creatorcontrib>Fox, W.B.</creatorcontrib><title>Growth of superconducting thin films of bismuth-strontium-calcium-copper oxide by organometallic chemical vapor deposition</title><title>Journal of crystal growth</title><description>The first growth of superconducting Bi-Sr-Ca-Cu-O films by organometallic chemical vapor deposition is described. Triphenyl bismuth and beta-diketonates of strontium, calcium, and copper were decomposed thermally at 500°C on MgO substrates in an oxygen-rich atmosphere to produce fine grained or amorphous, dark brown to black films. Subsequent annealing in oxygen yielded gray-black films with thicknesses of 0.95 to 1.25 μm. X-ray analysis indicated the presence of a tetragonal superconducting phase along with other metal oxides. The sheet resistance versus temperature for the sample with the highest
T
c had a resistive transition with a midpoint at 78.8 K, a width of 7.7 K, and
R = 0 at 73.2 K.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Physics</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><subject>Thin film structure and morphology</subject><issn>0022-0248</issn><issn>1873-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1988</creationdate><recordtype>article</recordtype><recordid>eNp9kMFu1TAQRS1UJF5L_6ALL1BVFgE7cRJng4QqKJUqsYG15djjvkGJndpOS_l6nL6qy65mMefe0RxCzjj7xBnvPjNW1xWrhbyQ8uPARM8q-YbsuOybqi3LI7J7Qd6R45T-MFZynO3Iv6sYHvKeBkfTukA0wdvVZPS3NO_RU4fTnLbtiGle875KOQafcZ0royfzNMNSgjT8RQt0fKQh3mofZsh6mtBQs4cZC0vv9RIitbCEhBmDf0_eOj0lOH2eJ-T392-_Ln9UNz-vri-_3lRGNCxXFhre1kMD7QBaWKgHqG0rmOucZZ1sXdeJvhtb0cpGaM1Ha1ingbUj67k1rjkh54feJYa7FVJWMyYD06Q9hDWpImXoBykKKA6giSGlCE4tEWcdHxVnahOtNotqs6ikVE-ilSyxD8_9OpU_XdTeYHrJ9o0YGrG1fzlgUH69R4gqGQRvwGIEk5UN-Pqd_1BIlM8</recordid><startdate>19881001</startdate><enddate>19881001</enddate><creator>Berry, A.D.</creator><creator>Holm, R.T.</creator><creator>Cukauskas, E.J.</creator><creator>Fatemi, M.</creator><creator>Gaskill, D.K.</creator><creator>Kaplan, R.</creator><creator>Fox, W.B.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19881001</creationdate><title>Growth of superconducting thin films of bismuth-strontium-calcium-copper oxide by organometallic chemical vapor deposition</title><author>Berry, A.D. ; Holm, R.T. ; Cukauskas, E.J. ; Fatemi, M. ; Gaskill, D.K. ; Kaplan, R. ; Fox, W.B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c430t-de315293e59ea4de29e2d540f6fd0685f66476b545834aa1bdc06ae05b071dcf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1988</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Physics</topic><topic>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</topic><topic>Thin film structure and morphology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Berry, A.D.</creatorcontrib><creatorcontrib>Holm, R.T.</creatorcontrib><creatorcontrib>Cukauskas, E.J.</creatorcontrib><creatorcontrib>Fatemi, M.</creatorcontrib><creatorcontrib>Gaskill, D.K.</creatorcontrib><creatorcontrib>Kaplan, R.</creatorcontrib><creatorcontrib>Fox, W.B.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of crystal growth</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Berry, A.D.</au><au>Holm, R.T.</au><au>Cukauskas, E.J.</au><au>Fatemi, M.</au><au>Gaskill, D.K.</au><au>Kaplan, R.</au><au>Fox, W.B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Growth of superconducting thin films of bismuth-strontium-calcium-copper oxide by organometallic chemical vapor deposition</atitle><jtitle>Journal of crystal growth</jtitle><date>1988-10-01</date><risdate>1988</risdate><volume>92</volume><issue>1</issue><spage>344</spage><epage>347</epage><pages>344-347</pages><issn>0022-0248</issn><eissn>1873-5002</eissn><coden>JCRGAE</coden><abstract>The first growth of superconducting Bi-Sr-Ca-Cu-O films by organometallic chemical vapor deposition is described. Triphenyl bismuth and beta-diketonates of strontium, calcium, and copper were decomposed thermally at 500°C on MgO substrates in an oxygen-rich atmosphere to produce fine grained or amorphous, dark brown to black films. Subsequent annealing in oxygen yielded gray-black films with thicknesses of 0.95 to 1.25 μm. X-ray analysis indicated the presence of a tetragonal superconducting phase along with other metal oxides. The sheet resistance versus temperature for the sample with the highest
T
c had a resistive transition with a midpoint at 78.8 K, a width of 7.7 K, and
R = 0 at 73.2 K.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/0022-0248(88)90470-8</doi><tpages>4</tpages></addata></record> |
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subjects | Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Physics Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) Thin film structure and morphology |
title | Growth of superconducting thin films of bismuth-strontium-calcium-copper oxide by organometallic chemical vapor deposition |
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