FTIR measurements of iron oxides on low alloy steel

Well-resolved FTIR spectra of iron oxide and iron carbonate corrosion scales are readily measurable with commercial instrumentation on otherwise untreated low alloy steel coupons. These spectra are relatable to the chemical history of the corrosion process. The absorption maxima of most of the 11 cr...

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Veröffentlicht in:Journal of the Electrochemical Society 1988-03, Vol.135 (3), p.551-556
Hauptverfasser: JASINSKI, R, ASFAHA LOB
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ASFAHA LOB
description Well-resolved FTIR spectra of iron oxide and iron carbonate corrosion scales are readily measurable with commercial instrumentation on otherwise untreated low alloy steel coupons. These spectra are relatable to the chemical history of the corrosion process. The absorption maxima of most of the 11 crystalline iron oxides and iron carbonate are sufficiently separated from one another to allow "fingerprinting" many of the films/scales. Exposing some of these films to vacuum, drastically alters the position of the absorption maxima. Forming such scales into KBr pellets can also alter the absorption maxima, depending on the particular oxide composition. 26 ref.--AA
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1945-7111
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source IOP Publishing Journals
subjects Applied sciences
Corrosion
Corrosion mechanisms
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Metals, semimetals and alloys
Metals. Metallurgy
Physics
Specific materials
title FTIR measurements of iron oxides on low alloy steel
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