Dissolution Behaviour of Copper and Nickel Oxides in Molten Li sub(2)CO sub(3)/Na sub(2) CO sub(3)/K sub(2)CO sub(3)

Dissolution Behaviour of Copper and Nickel Oxides in Molten Li sub(2)CO sub(3)/Na sub(2) CO sub(3)/K sub(2)CO sub(3)

An Li sub(2)CO sub(3)/Na sub(2)CO sub(3)/K sub(2)CO sub(3) eutectic melt has been taken as a typical example of a molten carbonate system, and the dissolution behaviour of the oxides of nickel and copper in the melt have been investigated at 873 K. The solubility products of CuO and NiO in the melt...

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Veröffentlicht in:Journal of power sources 1988-07, Vol.23 (4), p.357-357
Hauptverfasser: Ito, Yasuhiko, Tsuru, Kiyoshi, Oishi, Jun, Miyazaki, Yoshinori, Kodama, Teruo
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container_end_page 357
container_issue 4
container_start_page 357
container_title Journal of power sources
container_volume 23
creator Ito, Yasuhiko
Tsuru, Kiyoshi
Oishi, Jun
Miyazaki, Yoshinori
Kodama, Teruo
description An Li sub(2)CO sub(3)/Na sub(2)CO sub(3)/K sub(2)CO sub(3) eutectic melt has been taken as a typical example of a molten carbonate system, and the dissolution behaviour of the oxides of nickel and copper in the melt have been investigated at 873 K. The solubility products of CuO and NiO in the melt have been estimated to be 8.9 x 10 super(-9) mol super(2) l super(-2) and 3.8 ( plus or minus 0.6) x 10 super(-10) mol super(2) l super(-2), respectively. The diffusion coefficients of Cu(II) and Ni(II) ions in the melt are approximately 7.2 x 10 super(-5) cm super(2) s super(-1) and 2.2( plus or minus 0.5) x 10 super(-5) cm super(2) s super(-1), respectively.
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title Dissolution Behaviour of Copper and Nickel Oxides in Molten Li sub(2)CO sub(3)/Na sub(2) CO sub(3)/K sub(2)CO sub(3)
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