Properties of the tert-butyl halide solvolysis transition states

We have obtained properties (or descriptors) of the transition states in the solvolysis of tert-butyl chloride, bromide and iodide. We show that all three transition states, in both protic and in aprotic solvents, are highly dipolar and are strong hydrogen bond acids and strong hydrogen bond bases,...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2021-02, Vol.23 (5), p.3311-3320
Hauptverfasser:	Abraham, Mchael, martins, filomena, Elvas Leitao, Ruben, Moreira, Luís
Format:	Artikel
Sprache:	eng
Schlagworte:	Electrophilic Halides Hydrogen bonds Nucleophiles Nucleophilic Properties Solvents Solvolysis
Online-Zugang:	Volltext
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