Distinct structure assembly driven by metal–ligand binding in Au23 nanoclusters and its relation to photocatalysis
Here, we introduce two Au23 nanoclusters to unveil the significance of metal–ligand binding-induced assembly. The Au23 cluster protected by the thiolate ligand is packed in the shell-by-shell arrangement, while the Au23 cluster capped by dual ligands of thiolate and PPh3 is constructed from the asse...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2021-01, Vol.57 (17), p.2176-2179 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Li, Shuohao Sun, Yongnan Wu, Chenyang Hu, Weigang Li, Wei Liu, Xu Chen, Mingyang Zhu, Yan |
| description | Here, we introduce two Au23 nanoclusters to unveil the significance of metal–ligand binding-induced assembly. The Au23 cluster protected by the thiolate ligand is packed in the shell-by-shell arrangement, while the Au23 cluster capped by dual ligands of thiolate and PPh3 is constructed from the assembly of Au4 tetrahedra. Furthermore Au23 from Au4 tetrahedron-based assembly is capable of converting absorbed visible light into more excitons, compared to Au23 from shell-by-shell assembly, thus exhibiting more efficient photocatalysis. |
| doi_str_mv | 10.1039/d0cc08327e |
| format | Article |
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Furthermore Au23 from Au4 tetrahedron-based assembly is capable of converting absorbed visible light into more excitons, compared to Au23 from shell-by-shell assembly, thus exhibiting more efficient photocatalysis.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d0cc08327e</identifier><language>eng ; jpn</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Assembly ; Binding ; Clusters ; Crystallography ; Excitons ; Ligands ; Nanoclusters ; Photocatalysis ; Tetrahedra</subject><ispartof>Chemical communications (Cambridge, England), 2021-01, Vol.57 (17), p.2176-2179</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Li, Shuohao</creatorcontrib><creatorcontrib>Sun, Yongnan</creatorcontrib><creatorcontrib>Wu, Chenyang</creatorcontrib><creatorcontrib>Hu, Weigang</creatorcontrib><creatorcontrib>Li, Wei</creatorcontrib><creatorcontrib>Liu, Xu</creatorcontrib><creatorcontrib>Chen, Mingyang</creatorcontrib><creatorcontrib>Zhu, Yan</creatorcontrib><title>Distinct structure assembly driven by metal–ligand binding in Au23 nanoclusters and its relation to photocatalysis</title><title>Chemical communications (Cambridge, England)</title><description>Here, we introduce two Au23 nanoclusters to unveil the significance of metal–ligand binding-induced assembly. 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Furthermore Au23 from Au4 tetrahedron-based assembly is capable of converting absorbed visible light into more excitons, compared to Au23 from shell-by-shell assembly, thus exhibiting more efficient photocatalysis.</description><subject>Assembly</subject><subject>Binding</subject><subject>Clusters</subject><subject>Crystallography</subject><subject>Excitons</subject><subject>Ligands</subject><subject>Nanoclusters</subject><subject>Photocatalysis</subject><subject>Tetrahedra</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdkMtKAzEUhoMoWKsbnyDgxs1o7jNZlnqFghsFdyWTOakpaVInGaE738E39Emcoiv_zfkXHx_nHITOKbmihOvrjlhLGs5qOEATypWopGheD_dd6qrmQh6jk5zXZAyVzQSVG5-Lj7bgXPrBlqEHbHKGTRt2uOv9B0Tc7vAGignfn1_Br0zscOtj5-MK-4hnA-M4mphsGHKBPuM94EvGPQRTfIq4JLx9SyVZM0p22edTdORMyHD2N6fo5e72ef5QLZ7uH-ezRbWmrOaVcwK4qYEpoUhNnLKtaUFpxUwrO2ekc44AGM2MouNBSnDmaq1cJ6DlGvgUXf56t316HyCX5cZnCyGYCGnISyYaKSnTlI_oxT90nYY-jtuNlBZUj3-U_AdZQ24s</recordid><startdate>20210101</startdate><enddate>20210101</enddate><creator>Li, Shuohao</creator><creator>Sun, Yongnan</creator><creator>Wu, Chenyang</creator><creator>Hu, Weigang</creator><creator>Li, Wei</creator><creator>Liu, Xu</creator><creator>Chen, Mingyang</creator><creator>Zhu, Yan</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20210101</creationdate><title>Distinct structure assembly driven by metal–ligand binding in Au23 nanoclusters and its relation to photocatalysis</title><author>Li, Shuohao ; Sun, Yongnan ; Wu, Chenyang ; Hu, Weigang ; Li, Wei ; Liu, Xu ; Chen, Mingyang ; Zhu, Yan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-j1273-ff4e3a7e2646070f6cbabe6962ab5dfa5fff0eea92a610006432f796fd4eb39e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; jpn</language><creationdate>2021</creationdate><topic>Assembly</topic><topic>Binding</topic><topic>Clusters</topic><topic>Crystallography</topic><topic>Excitons</topic><topic>Ligands</topic><topic>Nanoclusters</topic><topic>Photocatalysis</topic><topic>Tetrahedra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Shuohao</creatorcontrib><creatorcontrib>Sun, Yongnan</creatorcontrib><creatorcontrib>Wu, Chenyang</creatorcontrib><creatorcontrib>Hu, Weigang</creatorcontrib><creatorcontrib>Li, Wei</creatorcontrib><creatorcontrib>Liu, Xu</creatorcontrib><creatorcontrib>Chen, Mingyang</creatorcontrib><creatorcontrib>Zhu, Yan</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Shuohao</au><au>Sun, Yongnan</au><au>Wu, Chenyang</au><au>Hu, Weigang</au><au>Li, Wei</au><au>Liu, Xu</au><au>Chen, Mingyang</au><au>Zhu, Yan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Distinct structure assembly driven by metal–ligand binding in Au23 nanoclusters and its relation to photocatalysis</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2021-01-01</date><risdate>2021</risdate><volume>57</volume><issue>17</issue><spage>2176</spage><epage>2179</epage><pages>2176-2179</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Here, we introduce two Au23 nanoclusters to unveil the significance of metal–ligand binding-induced assembly. 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| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2021-01, Vol.57 (17), p.2176-2179 |
| issn | 1359-7345 1364-548X |
| language | eng ; jpn |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Assembly Binding Clusters Crystallography Excitons Ligands Nanoclusters Photocatalysis Tetrahedra |
| title | Distinct structure assembly driven by metal–ligand binding in Au23 nanoclusters and its relation to photocatalysis |
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