Copolymerization of 5-vinyl-2,2'-bithiophene with methyl methacrylate and n-butyl acrylate

Copolymers of 5-vinyl-2,2'-bithiophene with methyl methacrylate or n-butyl acrylate were synthesized. Copolymer compositions were analyzed by nuclear magnetic resonance spectroscopy and reactivity ratios were calculated using the Kelen--Tudos method. 5-vinyl-2,2'-bithiophene proved to be a...

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Veröffentlicht in:Polymer bulletin (Berlin, Germany) Germany), 1988-03, Vol.19 (3), p.217-221
1. Verfasser: TRUMBO, D. L
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description Copolymers of 5-vinyl-2,2'-bithiophene with methyl methacrylate or n-butyl acrylate were synthesized. Copolymer compositions were analyzed by nuclear magnetic resonance spectroscopy and reactivity ratios were calculated using the Kelen--Tudos method. 5-vinyl-2,2'-bithiophene proved to be a very reactive monomer with a reactivity ratio value of greater than three in copolymerization reactions with methyl methacrylate and a value of greater than four in copolymerization reactions with n-butyl acrylate. 10 ref.--AA
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subjects Applied sciences
Copolymerization
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Copolymerization of 5-vinyl-2,2'-bithiophene with methyl methacrylate and n-butyl acrylate
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