Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties
Reactions of [SbBr6]3– containing HBr solutions with bromide salts of 1,1′-(1,2-ethanediyl)bis(pyridine) (PyC2 2+) or 1,1′-(1,2-ethanediyl)bis(3,5-dimethylpyridine) (3,5-MePyC2 2+) initially result in the formation of the deep orange complexes Cat[SbBr5] (1 and 2), featuring unusual Sb···Br int...
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| Veröffentlicht in: | Inorganic chemistry 2021-02, Vol.60 (4), p.2797-2804 |
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| creator | Usoltsev, Andrey N Sukhikh, Taisiya S Novikov, Alexander S Shayapov, Vladimir R Pishchur, Denis P Korolkov, Ilya V Sakhapov, Ilyas F Fedin, Vladimir P Sokolov, Maxim N Adonin, Sergey A |
| description | Reactions of [SbBr6]3– containing HBr solutions with bromide salts of 1,1′-(1,2-ethanediyl)bis(pyridine) (PyC2 2+) or 1,1′-(1,2-ethanediyl)bis(3,5-dimethylpyridine) (3,5-MePyC2 2+) initially result in the formation of the deep orange complexes Cat[SbBr5] (1 and 2), featuring unusual Sb···Br interactions in the solid state. In the mother liquor, 1 transforms into discrete binuclear (C2Py)2[Sb2Br10], which demonstrates polymorphism (triclinic 3 and monoclinic 4), while 2 transforms into polymeric (3,5-MePy){[SbBr4]} (5). DFT calculations reveal that the system of noncovalent Sb···Br contacts may be responsible for the appearance of the observed optical properties (unusual deep orange coloring). |
| doi_str_mv | 10.1021/acs.inorgchem.0c03699 |
| format | Article |
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In the mother liquor, 1 transforms into discrete binuclear (C2Py)2[Sb2Br10], which demonstrates polymorphism (triclinic 3 and monoclinic 4), while 2 transforms into polymeric (3,5-MePy){[SbBr4]} (5). DFT calculations reveal that the system of noncovalent Sb···Br contacts may be responsible for the appearance of the observed optical properties (unusual deep orange coloring).</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/acs.inorgchem.0c03699</identifier><identifier>PMID: 33496171</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Inorganic chemistry, 2021-02, Vol.60 (4), p.2797-2804</ispartof><rights>2021 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a351t-f7cc5d3d2565a08f772f32bc9dd946bc3b9d5dc0786f1c955c27be3e884ec15f3</citedby><cites>FETCH-LOGICAL-a351t-f7cc5d3d2565a08f772f32bc9dd946bc3b9d5dc0786f1c955c27be3e884ec15f3</cites><orcidid>0000-0001-9361-4594 ; 0000-0001-9913-5324 ; 0000-0002-9889-5273 ; 0000-0002-0532-6478 ; 0000-0001-5269-9130</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.0c03699$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.inorgchem.0c03699$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33496171$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Usoltsev, Andrey N</creatorcontrib><creatorcontrib>Sukhikh, Taisiya S</creatorcontrib><creatorcontrib>Novikov, Alexander S</creatorcontrib><creatorcontrib>Shayapov, Vladimir R</creatorcontrib><creatorcontrib>Pishchur, Denis P</creatorcontrib><creatorcontrib>Korolkov, Ilya V</creatorcontrib><creatorcontrib>Sakhapov, Ilyas F</creatorcontrib><creatorcontrib>Fedin, Vladimir P</creatorcontrib><creatorcontrib>Sokolov, Maxim N</creatorcontrib><creatorcontrib>Adonin, Sergey A</creatorcontrib><title>Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>Reactions of [SbBr6]3– containing HBr solutions with bromide salts of 1,1′-(1,2-ethanediyl)bis(pyridine) (PyC2 2+) or 1,1′-(1,2-ethanediyl)bis(3,5-dimethylpyridine) (3,5-MePyC2 2+) initially result in the formation of the deep orange complexes Cat[SbBr5] (1 and 2), featuring unusual Sb···Br interactions in the solid state. In the mother liquor, 1 transforms into discrete binuclear (C2Py)2[Sb2Br10], which demonstrates polymorphism (triclinic 3 and monoclinic 4), while 2 transforms into polymeric (3,5-MePy){[SbBr4]} (5). 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Chem</addtitle><date>2021-02-15</date><risdate>2021</risdate><volume>60</volume><issue>4</issue><spage>2797</spage><epage>2804</epage><pages>2797-2804</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Reactions of [SbBr6]3– containing HBr solutions with bromide salts of 1,1′-(1,2-ethanediyl)bis(pyridine) (PyC2 2+) or 1,1′-(1,2-ethanediyl)bis(3,5-dimethylpyridine) (3,5-MePyC2 2+) initially result in the formation of the deep orange complexes Cat[SbBr5] (1 and 2), featuring unusual Sb···Br interactions in the solid state. In the mother liquor, 1 transforms into discrete binuclear (C2Py)2[Sb2Br10], which demonstrates polymorphism (triclinic 3 and monoclinic 4), while 2 transforms into polymeric (3,5-MePy){[SbBr4]} (5). 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| source | ACS_美国化学学会期刊（与NSTL共建） |
| title | Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties |
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