Ultrafast Size Expansion and Turn‐On Luminescence of Atomically Precise Silver Clusters by Hydrogen Sulfide

The formation of high‐nuclearity silver(I) clusters remains elusive and their potential applications are still underdeveloped. Herein, we firstly prepared a chain‐like thiolated AgI complex {[Ag18(StBu)10(NO3)8(CH3CN)2(H2O)2] ⋅ [Ag18(StBu)10(NO3)8(CH3CN)6]}n (abbreviated as Ag18) in which two simila...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-04, Vol.60 (15), p.8505-8509
Hauptverfasser:	He, Wei‐Miao, Zhou, Zhe, Han, Zhen, Li, Si, Zhou, Zhan, Ma, Lu‐Fang, Zang, Shuang‐Quan
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions cluster to cluster transformation fluorescent probe Hydrogen sulfide Ionization Ions Mass spectrometry Mass spectroscopy Metal clusters Photoluminescence Photons Response time Silver silver(I) clusters Time dependence
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