E.s.c.a. studies of corona-discharge-treated polyethylene surfaces by use of gas-phase derivatization

Chemically specific gas-phase reactions have been used to tag corona-discharge-induced chemical species on the surface of polyethylene. These tag reactions provide distinct moieties that can be detected via e.s.c.a. to provide a surface count of induced species. Hydroxyl, epoxy, hydroperoxy, carboxy...

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Veröffentlicht in:	Polymer (Guilford) 1985-08, Vol.26 (8), p.1162-1166
Hauptverfasser:	Gerenser, L.J., Elman, J.F., Mason, M.G., Pochan, J.M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology gas-phase derivatization Organic polymers Physicochemistry of polymers polyethylene surfaces Properties and characterization Structure, morphology and analysis X-ray scattering for chemical analysis
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Zusammenfassung:	Chemically specific gas-phase reactions have been used to tag corona-discharge-induced chemical species on the surface of polyethylene. These tag reactions provide distinct moieties that can be detected via e.s.c.a. to provide a surface count of induced species. Hydroxyl, epoxy, hydroperoxy, carboxylic acid and carbonyl populations are discussed as a function of corona energy input, time after treatment and water washings.
ISSN:	0032-3861 1873-2291
DOI:	10.1016/0032-3861(85)90245-9