Conduction Band Control of Oxyhalides with a Triple-Fluorite Layer for Visible Light Photocatalysis
The discovery of building blocks offers new opportunities to develop and control properties of extended solids. Compounds with fluorite-type Bi2O2 blocks host various properties including lead-free ferroelectrics and photocatalysts. In this study, we show that triple-layered Bi2MO4 blocks (M = Bi, L...
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| Veröffentlicht in: | Journal of the American Chemical Society 2021-02, Vol.143 (6), p.2491-2499 |
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| creator | Nakada, Akinobu Kato, Daichi Nelson, Ryky Takahira, Hikaru Yabuuchi, Masayoshi Higashi, Masanobu Suzuki, Hajime Kirsanova, Maria Kakudou, Naoji Tassel, Cédric Yamamoto, Takafumi Brown, Craig M Dronskowski, Richard Saeki, Akinori Abakumov, Artem Kageyama, Hiroshi Abe, Ryu |
| description | The discovery of building blocks offers new opportunities to develop and control properties of extended solids. Compounds with fluorite-type Bi2O2 blocks host various properties including lead-free ferroelectrics and photocatalysts. In this study, we show that triple-layered Bi2MO4 blocks (M = Bi, La, Y) in Bi2MO4Cl allow, unlike double-layered Bi2O2 blocks, to extensively control the conduction band. Depending on M, the Bi2MO4 block is truncated by Bi–O bond breaking, resulting in a series of n-zigzag chain structures (n = 1, 2, ∞ for M = Bi, La, Y, respectively). Thus, formed chain structures are responsible for the variation in the conduction band minimum (−0.36 to −0.94 V vs SHE), which is correlated to the presence or absence of mirror symmetry at Bi. Bi2YO4Cl shows higher photoconductivity than the most efficient Bi2O2-based photocatalyst with promising visible-light photocatalytic activity for water splitting. This study expands the possibilities of thickening (2D to 3D) and cutting (2D to 1D) fluorite-based blocks toward desired photocatalysis and other functions. |
| doi_str_mv | 10.1021/jacs.0c10288 |
| format | Article |
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Compounds with fluorite-type Bi2O2 blocks host various properties including lead-free ferroelectrics and photocatalysts. In this study, we show that triple-layered Bi2MO4 blocks (M = Bi, La, Y) in Bi2MO4Cl allow, unlike double-layered Bi2O2 blocks, to extensively control the conduction band. Depending on M, the Bi2MO4 block is truncated by Bi–O bond breaking, resulting in a series of n-zigzag chain structures (n = 1, 2, ∞ for M = Bi, La, Y, respectively). Thus, formed chain structures are responsible for the variation in the conduction band minimum (−0.36 to −0.94 V vs SHE), which is correlated to the presence or absence of mirror symmetry at Bi. Bi2YO4Cl shows higher photoconductivity than the most efficient Bi2O2-based photocatalyst with promising visible-light photocatalytic activity for water splitting. This study expands the possibilities of thickening (2D to 3D) and cutting (2D to 1D) fluorite-based blocks toward desired photocatalysis and other functions.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/jacs.0c10288</identifier><identifier>PMID: 33417448</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Journal of the American Chemical Society, 2021-02, Vol.143 (6), p.2491-2499</ispartof><rights>2021 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a368t-b6621c81794909b34f03006f0f64c7fed9e433dcfdb94afe5b374d7fb70f95d93</citedby><cites>FETCH-LOGICAL-a368t-b6621c81794909b34f03006f0f64c7fed9e433dcfdb94afe5b374d7fb70f95d93</cites><orcidid>0000-0002-8891-2033 ; 0000-0001-6670-5044 ; 0000-0002-3911-9864 ; 0000-0002-1925-9624 ; 0000-0002-7960-1014 ; 0000-0002-7135-4629 ; 0000-0001-8592-076X ; 0000-0001-7429-2200 ; 0000-0002-1600-4095</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jacs.0c10288$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jacs.0c10288$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33417448$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Nakada, Akinobu</creatorcontrib><creatorcontrib>Kato, Daichi</creatorcontrib><creatorcontrib>Nelson, Ryky</creatorcontrib><creatorcontrib>Takahira, Hikaru</creatorcontrib><creatorcontrib>Yabuuchi, Masayoshi</creatorcontrib><creatorcontrib>Higashi, Masanobu</creatorcontrib><creatorcontrib>Suzuki, Hajime</creatorcontrib><creatorcontrib>Kirsanova, Maria</creatorcontrib><creatorcontrib>Kakudou, Naoji</creatorcontrib><creatorcontrib>Tassel, Cédric</creatorcontrib><creatorcontrib>Yamamoto, Takafumi</creatorcontrib><creatorcontrib>Brown, Craig M</creatorcontrib><creatorcontrib>Dronskowski, Richard</creatorcontrib><creatorcontrib>Saeki, Akinori</creatorcontrib><creatorcontrib>Abakumov, Artem</creatorcontrib><creatorcontrib>Kageyama, Hiroshi</creatorcontrib><creatorcontrib>Abe, Ryu</creatorcontrib><title>Conduction Band Control of Oxyhalides with a Triple-Fluorite Layer for Visible Light Photocatalysis</title><title>Journal of the American Chemical Society</title><addtitle>J. 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| title | Conduction Band Control of Oxyhalides with a Triple-Fluorite Layer for Visible Light Photocatalysis |
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