Halide-Enhanced Spin–Orbit Coupling and the Phosphorescence Rate in Ir(III) Complexes

The spin-forbidden nature of phosphorescence in Ir­(III) complexes is relaxed by the metal-induced effect of spin–orbit coupling (SOC). A further increase of the phosphorescence rate could potentially be achieved by introducing additional centers capable of further enhancing the SOC effect, such as...

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Veröffentlicht in:	Inorganic chemistry 2021-01, Vol.60 (2), p.642-650
Hauptverfasser:	Shafikov, Marsel Z, Zaytsev, Andrey V, Kozhevnikov, Valery N
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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